A crossed-beam study of the reaction C(1D)+H2(X1Σ+,υ=0)→CH(X2Π,υ′)+H(2S)

被引：66
作者：
Bergeat, A
Cartechini, L
Balucani, N
Capozza, G
Phillips, LF
Casavecchia, P [1 ]
Volpi, GG
Bonnet, L
Rayez, JC
机构：
[1] Dipartimento Chim, I-06123 Perugia, Italy
[2] Univ Bordeaux 1, Lab Physicochim Mol, F-33405 Talence, France
[3] Univ Bordeaux 1, Dept Mesures Phys, IUT A, F-33405 Talence, France
来源：
CHEMICAL PHYSICS LETTERS | 2000年 / 327卷 / 3-4期
关键词：
D O I：
10.1016/S0009-2614(00)00870-8
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Product angular and time-of-flight distributions have been measured for the first time for the prototypical insertion reaction C(D-1) + H-2 using the crossed-beam technique with mass spectrometric detection at the collision energy of 1.86 kcal mol(-1). Center-of-mass angular and kinetic energy distributions have been derived for CH(X(2)Pi, nu', = 0) + H products and compared with those of statistical calculations based on phase-space theory. (C) 2000 Elsevier Science B.V. All rights reserved.
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页码：197 / 202
页数：6
相关论文
共 36 条
  • [1] THE INITIAL PRODUCT VIBRATIONAL-ENERGY DISTRIBUTION IN THE REACTION BETWEEN O(1D2) AND H2
    AKER, PM
    SLOAN, JJ
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1986, 85 (03) : 1412 - 1417
  • [2] Alagia M, 1997, ISR J CHEM, V37, P329
  • [3] Exploring the reaction dynamics of nitrogen atoms:: A combined crossed beam and theoretical study of N(2D)+D2→ND+D
    Alagia, M
    Balucani, N
    Cartechini, L
    Casavecchia, P
    Volpi, GG
    Pederson, LA
    Schatz, GC
    Lendvay, G
    Harding, LB
    Hollebeek, T
    Ho, TS
    Rabitz, H
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1999, 110 (18) : 8857 - 8860
  • [4] Crossed molecular beams and quasiclassical trajectory studies of the reaction O(1D)+H2(D2)
    Alagia, M
    Balucani, N
    Cartechini, L
    Casavecchia, P
    van Kleef, EH
    Volpi, GG
    Kuntz, PJ
    Sloan, JJ
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1998, 108 (16) : 6698 - 6708
  • [5] REACTIVE SCATTERING OF ATOMS AND RADICALS
    ALAGIA, M
    BALUCANI, N
    CASAVECCHIA, P
    STRANGES, D
    VOLPI, GG
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1995, 91 (04): : 575 - 596
  • [6] O(1D2)+H2→OH|v′≤4,N′⟩+H -: The anatomy of a reaction
    Alexander, AJ
    Blunt, DA
    Brouard, M
    Simons, JP
    Aoiz, FJ
    Banares, L
    Fujimura, Y
    Tsubouchi, M
    [J]. FARADAY DISCUSSIONS, 1997, 108 : 375 - 386
  • [7] BERGEAT A, IN PRESS
  • [8] AB-INITIO POTENTIAL-ENERGY SURFACES FOR REACTIONS OF ATOMIC CARBON WITH MOLECULAR-HYDROGEN
    BLINT, RJ
    NEWTON, MD
    [J]. CHEMICAL PHYSICS LETTERS, 1975, 32 (01) : 178 - 183
  • [9] Some key factors of energy distributions in the products of complex-forming elementary reactions
    Bonnet, L
    Rayez, JC
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1999, 1 (10) : 2383 - 2400
  • [10] BONNET L, UNPUB
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