Optimization of ZnxFe3-xO4 Hollow Spheres for Enhanced Microwave Attenuation

被引:69
作者
Yang, Zhihong [1 ,2 ]
Li, Zhengwen [1 ]
Yang, Yanhui [2 ]
Xu, Zhichuan J. [3 ]
机构
[1] Natl Univ Singapore, Temasek Labs, Singapore 117411, Singapore
[2] Nanyang Technol Univ, Sch Chem & Biomed Engn, Singapore 637459, Singapore
[3] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore
关键词
hollow spheres; magnetic materials; solvothermal process; microwave attenuation; ABSORPTION PROPERTIES; MAGNETIC-PROPERTIES; ZINC FERRITE; NANOPARTICLES;
D O I
10.1021/am5075612
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
We report here the composition optimization of ZnxFe3-xO4 hollow nanospheres for enhancing microwave attenuation. ZnxFe3-xO4 hollow nanospheres were synthesized through a simple solvothermal process. The maximum magnetization moment of 91.9 emu/g can be obtained at x = 0.6. The composite filled with Zn0.6Fe2.4O4 exhibited the bandwidth of 3.21-8.33 GHz for RL < -10 dB and a maximum relative bandwidth (Wp,max) of 88.6% at optimized thickness t0 = 0.34 cm. The enhancement should be attributed to the enhanced permeability resonance at high frequency. This optimized hollow material is very promising to be used as a mass efficient and broadband microwave attenuation material. © 2014 American Chemical Society.
引用
收藏
页码:21911 / 21915
页数:5
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