A visually detectable pH responsive zirconium metal-organic framework

被引：56

作者：

Moon, Su-Young ^{[1
]}

Howarth, Ashlee J. ^{[1
]}

Wang, Timothy ^{[1
]}

Vermeulen, Nicolaas A. ^{[1
]}

Hupp, Joseph T. ^{[1
]}

Farha, Omar K. ^{[1
,2
]}

机构：

[1] Northwestern Univ, Dept Chem, 2145 Sheridan Rd, Evanston, IL 60208 USA

[2] Univ Jeddah, Fac Sci King Abdulaziz, Dept Chem, Jeddah, Saudi Arabia

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 16期

关键词：

ASSISTED LIGAND INCORPORATION; CHEMICAL-WARFARE AGENTS; FUNCTIONALIZATION; MACROPHAGES; HYDROLYSIS; ADSORPTION; DEPOSITION; SIMULANTS; NU-1000; STORAGE;

D O I：

10.1039/c5cc10384c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A halochromic Zr-6-based metal-organic framework is synthesized using solvent-assisted linker incorporation (SALI) with NU-1000 as a platform and carboxylnaphthofluorescein as a pH sensitive ligand. The functionalizedMOF can catalytically detoxify nerve agent simulants in addition to visually detecting the acidic byproduct produced during detoxification.

引用

页码：3438 / 3441

页数：4

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