Hydrocarbon bridged metal complexes:: XLII.: Addition of aniline tricarbonyl chromium complexes to the dienyl ligands of [(η5-H3CC5H5CH3)Fe(CO)3]+ and [(η5-C5H6CH3)Fe(CO)3]+

被引：3

作者：

Bentele, HJ ^{[1
]}

Sunkel, K ^{[1
]}

Beck, W ^{[1
]}

机构：

[1] Univ Munich, Inst Anorgan Chem, D-80333 Munich, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 549卷 / 1-2期

关键词：

carbonyl chromium complexes; carbonyl iron complexes; N-((E)-1-methyl-2,4-pentadienyl)aniline; N-methyl-N-((2E,4E)-1-methyl-2,4-hexadienyl)aniline;

D O I：

10.1016/S0022-328X(97)00505-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Aniline tricarbonyl chromium complexes (eta(6)-C6H4(R)NHR1)Cr(CO)(3) (R = H, CH3; R-1 = H, CH3) were used as nucleophiles for addition to [(eta(5)-H3CC5H5CH3)Fe(CO)(3)](+) and [(eta(5)-C5H6CH3)Fe(CO)(3)](+) to give the heterobimetallic ligand bridged complexes (OC)(3)Cr(eta(6)-C6H4(R)N(R-1)(CH3)C5H5CH3-eta(4))Fe(CO)(3) and (OC)(3)Cr(eta(6)-C6H4(R)N(R-1)C5H6CH3-eta(4))Fe(CO)(3). The structures of (OC)(3)Cr(eta(6)-C6H4(CH3)N(H)(CH3)C5H5CH3-eta(4))Fe(CO)(3) and (OC)(3)Cr(eta(6)-C6H5N(H)C5H6CH3-eta(4))Fe(CO)(3) were determined by X-ray diffraction. (C) 1997 Elsevier Science S.A.

引用

页码：245 / 250

页数：6

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[1] Hydrocarbon bridged metal complexes: XLII. Addition of aniline tricarbonyl chromium complexes to the dienyl ligands of [(eta5-H3CC5H5CH3)Fe(CO)3]+$ / and [(eta$+5-C5H6CH3)Fe(CO)3]+
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