Solid-phase synthesis of chiral modular ferrocene-based peptides

被引：46

作者：

Heinze, Katia ^{[1
]}

Wild, Ute ^{[1
]}

Beckmann, Manuela ^{[1
]}

机构：

[1] Heidelberg Univ, Inst Anorgan Chem, D-69120 Heidelberg, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2007年 / 04期

关键词：

conformation analysis; hydrogen bonds; metallocenes; molecular modelling; solid-phase synthesis;

D O I：

10.1002/ejic.200600857

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ferrocene-containing tripeptides with one to two ferrocene building blocks were prepared by solid-phase peptide synthesis (SPPS) using Fmoc-protected 1'-aminoferrocene-1-carboxylic acid (Fca). The conformations of the tripeptides were analysed by spectroscopic and theoretical methods. The immobilised ferrocene compounds can be reversibly oxidised on-bead to positively charged peptides and were analysed for anion-binding affinities by a solid-phase binding assay. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

引用

页码：617 / 623

页数：7

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