Rhodium(I) complexes of unsymmetrical diphosphines: efficient and stable methanol carbonylation catalysts

被引：54

作者：

Carraz, CA

Ditzel, EJ

Orpen, AG

Ellis, DD

Pringle, PG

Sunley, GJ

机构：

[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

[2] BP Chem, Hull Res & Technol Ctr, Hull HU12 8DS, N Humberside, England

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 14期

关键词：

D O I：

10.1039/b002802i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rhodium complexes of unsymmetrical diphosphines of the type Ph2PCH2CH2PAr2 are catalysts for the carbonylation of methanol; several features of the catalysis are reminiscent of iridium carbonylation catalysts.

引用

页码：1277 / 1278

页数：2

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