Quantum Diffusion on Molecular Tubes: Universal Scaling of the 1D to 2D Transition

被引:38
作者
Chuang, Chern [1 ]
Lee, Chee Kong [1 ]
Moix, Jeremy M. [1 ]
Knoester, Jasper [2 ]
Cao, Jianshu [1 ]
机构
[1] MIT, Dept Chem, Cambridge, MA 02139 USA
[2] Univ Groningen, Zernike Inst Adv Mat, Nijenborgh 4, NL-9747 AG Groningen, Netherlands
基金
美国国家科学基金会;
关键词
ELECTRONIC SPECTROSCOPY; INDIVIDUAL CHLOROSOMES; CHLOROBACULUM-TEPIDUM; EXCITON-TRANSITIONS; MICROSCOPIC MODEL; ENERGY-TRANSFER; DYE NANOTUBES; DISORDER; SPECTRA; BACTERIOCHLOROPHYLLS;
D O I
10.1103/PhysRevLett.116.196803
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The transport properties of disordered systems are known to depend critically on dimensionality. We study the diffusion coefficient of a quantum particle confined to a lattice on the surface of a tube, where it scales between the 1D and 2D limits. It is found that the scaling relation is universal and independent of the temperature, disorder, and noise parameters, and the essential order parameter is the ratio between the localization length in 2D and the circumference of the tube. Phenomenological and quantitative expressions for transport properties as functions of disorder and noise are obtained and applied to real systems: In the natural chlorosomes found in light-harvesting bacteria the exciton transfer dynamics is predicted to be in the 2D limit, whereas a family of synthetic molecular aggregates is found to be in the homogeneous limit and is independent of dimensionality.
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页数:6
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