A novel hydrophilic amino acid ionic liquid [C2OHmim][Gly] as aqueous sorbent for CO2 capture

被引:40
作者
Lv, Bihong [1 ,2 ]
Xia, Yinfeng [1 ]
Shi, Yun [1 ]
Liu, Nan [1 ]
Li, Wei [1 ]
Li, Sujing [1 ]
机构
[1] Zhejiang Univ, Inst Ind Ecol & Environm, Coll Chem & Biol Engn, Key Lab Biomass Chem Engn,Minist Educ, Yuquan Campus, Hangzhou 310027, Peoples R China
[2] Huaqiao Univ, Coll Chem Engn, Dept Environm Sci & Engn, Xiamen 361021, Fujian, Peoples R China
基金
中国国家自然科学基金;
关键词
Absorption; CO2; Amino acid; Functionalized; Ionic liquid; CARBON-DIOXIDE ABSORPTION; 2-AMINO-2-METHYL-1-PROPANOL AMP; REGENERATION PERFORMANCE; MONOETHANOLAMINE MEA; POTASSIUM-SALT; MASS-TRANSFER; KINETICS; SOLUBILITY; ALKANOLAMINES; TAURINE;
D O I
10.1016/j.ijggc.2015.12.029
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Since functionalized ionic liquid (ILs) could achieve excellent performance on CO2 capture by introducing suitable moieties in the conventional ionic liquids, design and synthesis of new ionic liquids have been attracting remarkable interests. In this work, we designed a novel hydrophilic amino acid ionic liquid ([C(2)OHmim][Gly]) that was functionalized based on the imidazolium ionic liquid with glycine anions and hydroxy group for CO2 absorption. The absorption capacity of [C(2)OHmim][Gly] was 0.575 mol CO2/mol absorbent that was similar to the equimolar stoichiometry following the zwitterion mechanism. Simple synthesis, large absorption capacity, good resistance to O-2, and high regeneration efficiency make this functionalized Its great potential for making up the deficiencies of aqueous MEA, therefore benefiting industrial applications. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1 / 6
页数:6
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