One-pot synthesis of 3D-ZIF-7 supported on 2D-Zn-Benzimidazole-Acetate and its catalytic activity in the methoxycarbonylation of aniline with dimethyl carbonate

被引：6
作者：
Dahnum, Deliana [1 ,2 ,3 ]
Dang, Huyen Tran [1 ,2 ]
Tran, Ngoc Tuan [1 ,2 ]
Ha, Jeong-Myeong [1 ,2 ]
Lee, Hyunjoo [1 ,2 ]
机构：
[1] Korea Inst Sci & Technol, Clean Energy Res Ctr, 5,Hwarang Ro,14 Gil, Seoul 02792, South Korea
[2] Korea Univ Sci & Technol, KIST Sch, Div Energy & Environm Technol, Seoul 02792, South Korea
[3] Indonesian Inst Sci, Res Ctr Chem, LIPI Lembaga Ilmu Pengetahuan Indonesia, Serpong 15314, Tangerang Selat, Indonesia
来源：
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY | 2021年 / 99卷
基金：
新加坡国家研究基金会;
关键词：
ZIF-7; Zn(BeIM)OAc; One-pot synthesis; Methoxycarbonylation; N-PHENYL CARBAMATE; ZEOLITIC IMIDAZOLATE FRAMEWORK; EFFICIENT HETEROGENEOUS CATALYST; ZIF-8; SEPARATION; STABILITY; SOLVENT; DIAMINE;
D O I：
10.1016/j.jiec.2021.04.049
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
For the first time, three-dimensional Zeolitic Imidazole Framework (3D) ZIF-7 (Zn(BeIM)(2), BeIM = benzimidazole) supported on two-dimensional (2D) Zn(BeIM)OAc (Zinc-Benzimidazole-Acetate) was synthesized by reacting Zn(OAc)(2) and benzimidazole in a one-pot reaction. By modulating the amount of diethylamine during the reaction, the ZIF-7/Zn(BeIM)OAc with a 1 to 1 molar ratio was obtained when the reactant molar ratio of Zn(OAc)(2) and benzimidazole was 1 to 1.5. It was found that 3D-ZIF-7 was synthesized first and then transformed into 2D-Zn(BeIM)OAc by the reaction with remaining Zn(OAc)(2). The synthesized ZIF-7 (Zn(BeIM)(2)) supported on Zn(BeIM)OAc (1/1) showed enhanced catalytic performance in the methoxycarbonylation of aniline with dimethyl carbonate. The yield of methyl N-phenyl carbamate reached 92.0% in 2 h at 190 degrees C, which was higher than yields obtained using the single component catalysts ZIF-7 (69.9%) and Zn(BeIM)OAc (35.4%). Furthermore, this catalyst was successfully reused four times, maintaining an MPC yield of 92.0%-95.8%. (C) 2021 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：380 / 387
页数：8
相关论文
共 46 条
[1]   Characteristics of methoxycarbonylation of aromatic diamine with dimethyl carbonate to dicarbamate using a zinc acetate catalyst [J].
Baba, T ;
Kobayashi, A ;
Kawanami, Y ;
Inazu, K ;
Ishikawa, A ;
Echizenn, T ;
Murai, K ;
Aso, S ;
Inomata, M .
GREEN CHEMISTRY, 2005, 7 (03) :159-165
[2]   Catalytic synthesis of N-alkyl carbamates by methoxycarbonylation of alkylamines with dimethyl carbonate using Pb(NO3)2 [J].
Baba, T ;
Fujiwara, M ;
Oosaku, A ;
Kobayashi, A ;
Deleon, RG ;
Ono, Y .
APPLIED CATALYSIS A-GENERAL, 2002, 227 (1-2) :1-6
[3]   A room temperature synthesizable zeolitic imidazolium framework catalyst for the solvent-free synthesis of cyclic carbonates [J].
Babu, Robin ;
Kim, Seol-Hee ;
Kurisingal, Jintu Francis ;
Kim, Hyeon-Jun ;
Choi, Gak-Gyu ;
Park, Dae-Won .
JOURNAL OF CO2 UTILIZATION, 2018, 25 :6-13
[4]   Thermal Structural Transitions and Carbon Dioxide Adsorption Properties of Zeolitic Imidazolate Framework-7 (ZIF-7) [J].
Cai, Wanxi ;
Lee, Taehee ;
Lee, Maro ;
Cho, Woosuk ;
Han, Doug-Young ;
Choi, Nakwon ;
Yip, Alex C. K. ;
Choi, Jungkyu .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (22) :7961-7971
[5]   Controlling Zeolitic Imidazolate Framework Nano- and Microcrystal Formation: Insight into Crystal Growth by Time-Resolved In Situ Static Light Scattering [J].
Cravillon, Janosch ;
Nayuk, Roman ;
Springer, Sergej ;
Feldhoff, Armin ;
Huber, Klaus ;
Wiebcke, Michael .
CHEMISTRY OF MATERIALS, 2011, 23 (08) :2130-2141
[6]   Carbamate synthesis from amines and dimethyl carbonate under ytterbium triflate catalysis [J].
Curini, M ;
Epifano, F ;
Maltese, F ;
Rosati, O .
TETRAHEDRON LETTERS, 2002, 43 (28) :4895-4897
[7]   Formation of defect site on ZIF-7 and its effect on the methoxycarbonylation of aniline with dimethyl carbonate [J].
Dahnum, Deliana ;
Seo, Bora ;
Cheong, Seok-Hyeon ;
Lee, Ung ;
Ha, Jeong-Myeong ;
Lee, Hyunjoo .
JOURNAL OF CATALYSIS, 2019, 380 :297-306
[8]  
Fabio A., 2011, PURE APPL CHEM, V695
[9]   SYNTHESIS OF METHYL N-PHENYL CARBAMATE BY METHOXYCARBONYLATION OF ANILINE WITH DIMETHYL CARBONATE USING PB COMPOUNDS AS CATALYSTS [J].
FU, ZH ;
ONO, Y .
JOURNAL OF MOLECULAR CATALYSIS, 1994, 91 (03) :399-405
[10]   The Molecular Pathway to ZIF-7 Microrods Revealed by In Situ Time-Resolved Small- and Wide-Angle X-Ray Scattering, Quick-Scanning Extended X-Ray Absorption Spectroscopy, and DFT Calculations [J].
Goesten, Maarten ;
Stavitski, Eli ;
Pidko, Evgeny A. ;
Gucuyener, Canan ;
Boshuizen, Bart ;
Ehrlich, Steven N. ;
Hensen, Emiel J. M. ;
Kapteijn, Freek ;
Gascon, Jorge .
CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (24) :7809-7816
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