Synthesis and Structure Investigation of a Transition Metal Ion Bridging Bis(diphosphopentamolybdates), [H2BIIM]3[HBIIM]4[Mn(H2O)4(P2Mo5O23)2]•7H2O

被引：0
|
作者：
Wei Lin-Heng [2 ]
Wang Zi-Liang [1 ]
Zhao Jun-Wei [1 ]
Wang Jing-Ping [1 ]
机构：
[1] Henan Univ, Coll Chem & Chem Engn, Kaifeng 475001, Peoples R China
[2] Henan Univ, Inst Nat Resources & Environm Sci, Coll Environm & Planning, Kaifeng 475001, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2010年 / 29卷 / 05期
关键词：
polyoxometalate; molybdate; crystal structure; dumbbell-like; phosphate; CLUSTER; NETWORK; CHEMISTRY;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel transition metal ion bridging bis(diphosphopentamolybdates) has been synthesized and characterized by elemental analysis, IR spectrum, UV spectrum and single-crystal X-ray diffraction. The single-crystal structure analysis shows that the compound consists of seven charge-compensating 2,2'-biimidazole cations (BIIM = 2,2'-biimidazole) and one dumbbell-like [Mn(H2O)(4)(P2Mo5O23)(2)](10-) heteropolyanion which is constructed by two [P2Mo5O23](6-) clusters bridged through one [Mn(H2O)(4)](2+) cation.
引用
收藏
页码：784 / 788
页数：5
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