Synthesis and Structure Investigation of a Transition Metal Ion Bridging Bis(diphosphopentamolybdates), [H2BIIM]3[HBIIM]4[Mn(H2O)4(P2Mo5O23)2]•7H2O

被引：0
作者：
Wei Lin-Heng [2 ]
Wang Zi-Liang [1 ]
Zhao Jun-Wei [1 ]
Wang Jing-Ping [1 ]
机构：
[1] Henan Univ, Coll Chem & Chem Engn, Kaifeng 475001, Peoples R China
[2] Henan Univ, Inst Nat Resources & Environm Sci, Coll Environm & Planning, Kaifeng 475001, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2010年 / 29卷 / 05期
关键词：
polyoxometalate; molybdate; crystal structure; dumbbell-like; phosphate; CLUSTER; NETWORK; CHEMISTRY;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel transition metal ion bridging bis(diphosphopentamolybdates) has been synthesized and characterized by elemental analysis, IR spectrum, UV spectrum and single-crystal X-ray diffraction. The single-crystal structure analysis shows that the compound consists of seven charge-compensating 2,2'-biimidazole cations (BIIM = 2,2'-biimidazole) and one dumbbell-like [Mn(H2O)(4)(P2Mo5O23)(2)](10-) heteropolyanion which is constructed by two [P2Mo5O23](6-) clusters bridged through one [Mn(H2O)(4)](2+) cation.
引用
收藏
页码：784 / 788
页数：5
相关论文
共 17 条
  • [1] A novel compound with an interpenetrating 2D network structure constructed by [Mo5P2O23] and Ni-4,4′-bipyridine components:: its synthesis, characterization and magnetic behaviour
    Chen, J
    Lu, SF
    Yu, RM
    Chen, ZN
    Huang, ZX
    Lu, CZ
    [J]. CHEMICAL COMMUNICATIONS, 2002, (22) : 2640 - 2641
  • [2] An unprecedented fivefold interpenetrating network based on polyoxometalate building blocks
    Fan, Linlin
    Xiao, Dongrong
    Wang, Enbo
    Li, Yangguang
    Su, Zhongming
    Wang, Xinlong
    Liu, Jia
    [J]. CRYSTAL GROWTH & DESIGN, 2007, 7 (04) : 592 - 594
  • [3] Efficient oxidative alkyne homocoupling catalyzed by a monomeric dicopper-substituted silicotungstate
    Kamata, Keigo
    Yamaguchi, Syuhei
    Kotani, Miyuki
    Yamaguchi, Kazuya
    Mizuno, Noritaka
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (13) : 2407 - 2410
  • [4] Hydrothermal assembly and structural characterisation of one- and two-dimensional organic/inorganic hybrid materials constructed from diphosphopentamolybdate(VI) clusters and {Cu(en)}2+ complex groups
    Lu, JJ
    Xu, Y
    Goh, NK
    Chia, LS
    [J]. CHEMICAL COMMUNICATIONS, 1998, (24) : 2733 - 2734
  • [5] Two novel diphosphopentamolybdate cluster supported transition metal complexes:: (H2bpy)0.5{[Ni(H2O)5][Ni(Hbpy)(H2O)4][Mo5P2O23]} and (H2bpy)0.5{[Co(H2O)5][Co(Hbpy)(H2O)4][IMo5P2O23]}
    Lu, Y
    Lü, J
    Wang, EB
    Guo, YQ
    Xu, XX
    Xu, L
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2005, 740 (1-3) : 159 - 163
  • [6] Hydrothermal synthesis and crystal structure of a novel three-dimensional supramolecular network containing cyclic water hexamers:: [Co(en)3]4[P2Mo5O23]2•9H2O(en = ethylenediamine)
    Ma, Y
    Lu, Y
    Wang, EB
    Xu, XX
    Guo, YQ
    Bai, XL
    Xu, L
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2006, 784 (1-3) : 18 - 23
  • [7] Self-assembly of four three-dimensional reduced molybdenum(V) phosphates decorated with transitional metal complexes
    Ma, Ying
    Li, Yangguang
    Wang, Enbo
    Lu, Ying
    Wang, Xinlong
    Xiao, Dongrong
    Xu, Xinxin
    [J]. INORGANICA CHIMICA ACTA, 2007, 360 (02) : 421 - 430
  • [8] Pope M.T, 1983, Heteropoly and Isopoly Oxometalates
  • [9] POLYOXOMETALATE CHEMISTRY - AN OLD FIELD WITH NEW DIMENSIONS IN SEVERAL DISCIPLINES
    POPE, MT
    MULLER, A
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (01): : 34 - 48
  • [10] Polyoxometalate embedding of a tetraruthenium(IV)-oxo-core by template-directed metalation of [γ-SIW10O36]8-:: A totally inorganic oxygen-evolving catalyst
    Sartorel, Andrea
    Carraro, Mauro
    Scorrano, Gianfranco
    De Zorzi, Rita
    Geremia, Silvano
    McDaniel, Neal D.
    Bernhard, Stefan
    Bonchio, Marcella
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (15) : 5006 - +
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