Oxidative dehydrogenation of ethane to ethylene with carbon dioxide over supported Ga, Fe, and Cr-containing catalysts

被引：11

作者：

Mishanin, I. I. ^{[1
,2
]}

Zizganova, A. I. ^{[2
]}

Bogdan, V. I. ^{[1
,2
]}

机构：

[1] Moscow MV Lomonosov State Univ, Bldg 3,1 Leninskie Gory, Moscow 119991, Russia

[2] Russian Acad Sci, ND Zelinsky Inst Organ Chem, 47 Leninsky Prosp, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2018年 / 67卷 / 06期

基金：

俄罗斯科学基金会;

关键词：

oxidative dehydrogenation; ethane; carbon dioxide; FeCr oxide systems; CO2; OXIDE; PERFORMANCE; ALKANES;

D O I：

10.1007/s11172-018-2175-7

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oxydative dehydrogenation of ethane to ethelene over Ga-, Fe- and Cr-oxide systems has been investigated. CO2 was used as an oxidizing agent. The activity and stability of the synthesized catalysts were studied. The most efficient catalytic system was selected and the experimental conditions for the optimal conversion/selectivity ratio were found.

引用

页码：1031 / 1034

页数：4

共 17 条

[1] THE OXIDATIVE DEHYDROGENATION OF ETHANE AND PROPANE AS AN ALTERNATIVE WAY FOR THE PRODUCTION OF LIGHT OLEFINS [J].

CAVANI, F ;

TRIFIRO, F .

CATALYSIS TODAY, 1995, 24 (03) :307-313

[2] Activity and characterization of modified Cr2O3/ZrO2 nano-composite catalysts for oxidative dehydrogenation of ethane to ethylene with CO2 [J].

Deng, Shuang ;

Li, Huiquan ;

Li, Songgeng ;

Zhang, Yi .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 268 (1-2) :169-175

[3] Effect of hydrogen combustion reaction on the dehydrogenation of ethane in a fixed-bed catalytic membrane reactor [J].

Hasany, Masoud ;

Malakootikhah, Mohammad ;

Rahmanian, Vahid ;

Yaghmaei, Soheila .

CHINESE JOURNAL OF CHEMICAL ENGINEERING, 2015, 23 (08) :1316-1325

[4] Structure dependency of Mo-V-O-based complex oxide catalysts in the oxidations of hydrocarbons [J].

Katou, T ;

Vitry, D ;

Ueda, W .

CATALYSIS TODAY, 2004, 91-2 :237-240

[5] Preparation and Characterization of Nanosized ZSM-5 Zeolite Using Kaolin and Investigation of Kaolin Content, Crystallization Time and Temperature Changes on the Size and Crystallinity of Products [J].

Khatamian, M. ;

Irani, M. .

JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2009, 6 (01) :187-194

[6] The selective oxidative activation of light alkanes. From supported vanadia to multicomponent bulk V-containing catalysts [J].

Lopez Nieto, Jose M. .

TOPICS IN CATALYSIS, 2006, 41 (1-4) :3-15

[7] OXIDATIVE DEHYDROGENATION OF LOWER ALKANES ON VANADIUM OXIDE-BASED CATALYSTS - THE PRESENT STATE-OF-THE-ART AND OUTLOOKS [J].

MAMEDOV, EA ;

CORBERAN, VC .

APPLIED CATALYSIS A-GENERAL, 1995, 127 (1-2) :1-40

[8] High-performance Cr/H-ZSM-5 catalysts for oxidative dehydrogenation of ethane to ethylene with CO2 as an oxidant [J].

Mimura, N ;

Takahara, I ;

Inaba, M ;

Okamoto, M ;

Murata, K .

CATALYSIS COMMUNICATIONS, 2002, 3 (06) :257-262

[9] A Process Integration Approach to the Assessment of CO2 Fixation through Dry Reforming [J].

Noureldin, Mohamed M. B. ;

Elbashir, Nimir O. ;

Gabriel, Kerron J. ;

El-Halwagi, Mahmoud M. .

ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2015, 3 (04) :625-636

[10]

Ramesh Y., 2014, APPL PETROCHEM RES, P1

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