Properties of a mixed-valent iron compound with the kagome lattice

被引:20
|
作者
Rao, CNR [1 ]
Paul, G
Choudhury, A
Sampathkumaran, EV
Raychaudhuri, AK
Ramasesha, S
Rudra, I
机构
[1] Jawaharlal Nehru Ctr Adv Sci Res, Chem & Phys Mat Unit, Bangalore 560064, Karnataka, India
[2] Jawaharlal Nehru Ctr Adv Sci Res, CSIR, Ctr Excellence Chem, Bangalore 560064, Karnataka, India
[3] Tata Inst Fundamental Res, Dept Condensed Matter Phys & Mat Sci, Bombay 400005, Maharashtra, India
[4] Indian Inst Sci, Dept Phys, Bangalore 560012, Karnataka, India
[5] Indian Inst Sci, Solid State & Struct Chem Unit, Bangalore 560012, Karnataka, India
来源
PHYSICAL REVIEW B | 2003年 / 67卷 / 13期
关键词
D O I
10.1103/PhysRevB.67.134425
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
An organically templated iron sulfate of the formula [HN(CH2)(6)NH][(FeFe2F6)-Fe-III-F-II(SO4)(2)].[H3O] possessing the kagome lattice has been prepared and characterized by single-crystal crystallography and other techniques. This mixed-valent iron compound shows complex magnetic properties including spin-glass behavior and magnetic hysteresis. The low-temperature specific heat data show deviation from the T-2 behavior found in two-dimensional frustrated systems. Simple calculations have been carried out to understand the properties of this kagome compound.
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页数:5
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