New molecular switch architectures

被引：181

作者：

Harris, Jared D. ^{[1
]}

Moran, Mark J. ^{[1
]}

Aprahamian, Ivan ^{[1
]}

机构：

[1] Dartmouth Coll, Dept Chem, Hanover, NH 03755 USA

来源：

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA | 2018年 / 115卷 / 38期

关键词：

molecular switches; molecular machines; photochromic compounds; ACCEPTOR STENHOUSE ADDUCTS; VISIBLE-LIGHT; HEMITHIOINDIGO PHOTOSWITCHES; NEGATIVE PHOTOCHROMISM; THERMAL-ISOMERIZATION; AZO-BF2; SWITCHES; BOND ROTATION; AZO DYES; MOTOR; CONFORMATION;

D O I：

10.1073/pnas.1714499115

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

In this paper we elaborate on recently developed molecular switch architectures and how these new systems can help with the realization of new functions and advancement of artificial molecular machines. Progress in chemically and photoinduced switches and motors is summarized and contextualized such that the reader may gain an appreciation for the novel tools that have come about in the past decade. Many of these systems offer distinct advantages over commonly employed switches, including improved fidelity, addressability, and robustness. Thus, this paper serves as a jumping-off point for researchers seeking new switching motifs for specific applications, or ones that address the limitations of presently available systems.

引用

页码：9414 / 9422

页数：9

共 89 条

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