Synthesis and Characterization of Two 2D Layered New Coordination Polymers of Co/Ni with the Ligand of 1,4-Bis(imidazol-1-ylmethyl)benzene

被引：0

作者：

Yang Xiao-Li ^{[1
]}

Zhang Jun ^{[1
]}

Li Yi-Zhi ^{[1
]}

Du Hong-Bin ^{[1
]}

You Xiao-Zeng ^{[1
]}

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Sch Chem & Chem Engn, Nanjing 210093, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2010年 / 26卷 / 03期

关键词：

1,4-bis(imidazol-1-ylmethyl)benzene; isophthalic acid; Co/Ni; 2D layered structure; coordination polymers; hydrogen bonds; ZEOLITIC IMIDAZOLATE FRAMEWORKS; CRYSTAL-STRUCTURE; BIX; NETWORK;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Using 1,4-bis(imidazol-1-ylmethyl)benzene (bix) and isophthalate (IPA) as co-ligands, two new Co/Ni coordination polymers, {[M(bix)(IPA)(H2O)]}(n) (M=Ni, 1; Co, 2) have been synthesized. Single crystal structural analyses reveal that 1 and 2 are isostructural and possess a 2D square sheet-like network. The metal ions are six-coordinated with three O atoms from two IPA ligands, one O atom of coordinated water and two N atoms of two bix ligands, respectively. The network can be described as an uninodal 4-connected 2D net with a point symbol of 4(4).6(2). CCDC: 759693, 1; 759694, 2.

引用

页码：374 / 378

页数：5

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