Carbocycles from donor-acceptor cyclopropanes

被引：456
作者：
Grover, Huck K. [1 ]
Emmett, Michael R. [1 ]
Kerr, Michael A. [1 ]
机构：
[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2015年 / 13卷 / 03期
关键词：
ENOL SILYL ETHERS; RING-OPENING-CYCLIZATION; ACID-CATALYZED-REACTIONS; E METHYL-ESTER; 3+2 CYCLOADDITION; METHYLENECYCLOPROPYL KETONES; SUBSTITUTED CYCLOPROPYL; OLEFIN PARTICIPATION; ASYMMETRIC-SYNTHESIS; EXPANSION REACTION;
D O I：
10.1039/c4ob02117g
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
This review summarizes research directed towards the formation of carbocyclic adducts from donor-acceptor cyclopropanes. The focus of the review is on annulation and cycloaddition reactions (both inter-and intramolecularly) mediated by Lewis or protic acid, bases, or thermal conditions. Rearrangements resulting in carbocycles and those reactions mediated by transition metal catalysis have been excluded.
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页码：655 / 671
页数：17
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