Carbocycles from donor-acceptor cyclopropanes

被引：446

作者：

Grover, Huck K. ^{[1
]}

Emmett, Michael R. ^{[1
]}

Kerr, Michael A. ^{[1
]}

机构：

[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2015年 / 13卷 / 03期

关键词：

ENOL SILYL ETHERS; RING-OPENING-CYCLIZATION; ACID-CATALYZED-REACTIONS; E METHYL-ESTER; 3+2 CYCLOADDITION; METHYLENECYCLOPROPYL KETONES; SUBSTITUTED CYCLOPROPYL; OLEFIN PARTICIPATION; ASYMMETRIC-SYNTHESIS; EXPANSION REACTION;

D O I：

10.1039/c4ob02117g

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This review summarizes research directed towards the formation of carbocyclic adducts from donor-acceptor cyclopropanes. The focus of the review is on annulation and cycloaddition reactions (both inter-and intramolecularly) mediated by Lewis or protic acid, bases, or thermal conditions. Rearrangements resulting in carbocycles and those reactions mediated by transition metal catalysis have been excluded.

引用

页码：655 / 671

页数：17

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