Study on solid electrolyte interphase excessive growth caused by Mn (II) deposition on silicon anode

被引：11

作者：

Chen, Haihui ^{[1
]}

Ma, Tianyi ^{[2
]}

Zeng, Yingying ^{[3
]}

Liu, Limin ^{[1
]}

Qiu, Xinping ^{[4
]}

机构：

[1] Jinggangshan Univ, Coll Chem & Chem Engn, Jian 343009, Jiangxi, Peoples R China

[2] China Automot Technol & Res Ctr Co Ltd CATARC, Tianjin Key Lab Evaluat Technol Elect Vehicles, Tianjin 300300, Peoples R China

[3] Jinggangshan Univ, Sch Mech & Elect Engn, Jian 343009, Jiangxi, Peoples R China

[4] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China

来源：

ELECTROCHIMICA ACTA | 2018年 / 282卷

关键词：

Silicon anode; Solid electrolyte interphase; Mn dissolution; Lithium-ion batteries; LITHIUM-ION BATTERIES; RECENT PROGRESS; ENERGY DENSITY; GRAPHITE ANODE; PERFORMANCE; ISSUES; FILM; COMPOSITES; CHALLENGES; STORAGE;

D O I：

10.1016/j.electacta.2018.06.086

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Silicon has been considered as one of the next generation high capacity anode materials. However, dissolution of cathode material in electrolyte, which is a general problem for lithium-ion batteries, hinders the industrial development of silicon anode. This paper designs electrochemical environment of Mn (II) dissolution to study the capacity fading of silicon anode. Electrochemical analysis and differential scanning calorimetry analysis reveals that Mn (II) will decrease the stability of solid electrolyte interphase, leading to acceleration of solid electrolyte interphase excessive growth and decreasing Columbic efficiency of anode. (C) 2018 Elsevier Ltd. All rights reserved.

引用

页码：602 / 608

页数：7

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