clay;
controlled radical polymerization;
in situ polymerization;
living polymerization;
nanocomposites;
POLYMER/LAYERED SILICATE NANOCOMPOSITES;
TRANSFER RADICAL POLYMERIZATION;
LAYERED SILICATE;
INTERCALATIVE POLYMERIZATION;
EPSILON-CAPROLACTONE;
POLY(EPSILON-CAPROLACTONE)/CLAY NANOCOMPOSITES;
POLY(ETHYL ACRYLATE)/CLAY;
BUTYL ACRYLATE;
ONE-POT;
CLAY;
D O I:
10.1002/macp.200900590
中图分类号:
O63 [高分子化学(高聚物)];
学科分类号:
070305 ;
080501 ;
081704 ;
摘要:
The present trend article reports on the recent progress of the in situ synthesis of polymer/clay nanocomposites with well-defined structures and highly exfoliated morphologies. The methods used for the preparation are classified according to the individual polymerization mechanisms. Other possibilities such as multi-mode polymerization that combines different polymerization methods and click chemistry are also described. A special emphasis is devoted to the structures and morphologies of the obtained nanocomposites rather than their practical properties.