Transformation in carbohydrate chemistry, Part 5. An efficient one step dihydroxylation of 1,2-glycals with oxone in acetone

被引:34
作者
Rani, S [1 ]
Vankar, YD [1 ]
机构
[1] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India
关键词
STEREOCONTROLLED SYNTHESIS; C-GLYCOSIDES; CONVERSION;
D O I
10.1016/S0040-4039(02)02774-0
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A number of glycals have been converted into the corresponding 1,2-diols in fair to good yields. The reaction appears to proceed via the corresponding epoxide which opens in situ. (C) 2003 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:907 / 909
页数:3
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