Hydrogen evolution reaction on Pt and Ru in alkali with volmer-step promotors and electronic structure modulators

被引：50

作者：

Anantharaj, Sengeni ^{[1
,2
]}

机构：

[1] Waseda Univ, Waseda Res Inst Sci & Engn, Shinjuku Ku, 3-4-1 Okubo, Tokyo 1698555, Japan

[2] Waseda Univ, Dept Appl Chem, Shinjuku Ku, 3-4-1 Okubo, Tokyo 1698555, Japan

来源：

CURRENT OPINION IN ELECTROCHEMISTRY | 2022年 / 33卷

关键词：

Electrocatalysis; Hydrogen evolution reaction; Pt; Ru; Metal chalcogenides; Metal phosphides; Metal hydroxides; EFFICIENT; ELECTROCATALYSTS; NI(OH)(2); NANOPARTICLES; PERFORMANCE; REDUCTION; CATALYSTS; DENSITY;

D O I：

10.1016/j.coelec.2022.100961

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Alkaline water electrolysis despite having a variety of choices for anodic oxygen evolution reaction (OER) catalysts out of non-precious metals suffers significantly due to the poor kinetics of cathodic hydrogen evolution reaction (HER) even with the state-of-the-art Pt and equally active Ru. The Volmer-step (water dissociation (WD) coupled proton adsorption) of alkaline HER is mostly the rate-determining step (RDS) and costs most of the work required. In this review, recent developments in improving the HER kinetics of Pt and Ru with Volmer-step promotors and electronic structure modulators have been comprehensively analyzed and critically presented with the challenges and prospects.

引用

页数：8

共 61 条

[1]

Adzic R., 2020, Platinum Monolayer Electrocatalysts, P35

[2] Ru-tweaking of non-precious materials: the tale of a strategy that ensures both cost and energy efficiency in electrocatalytic water splitting [J].

Anantharaj, S. .

JOURNAL OF MATERIALS CHEMISTRY A, 2021, 9 (11) :6710-6731

[3] "The Fe Effect": A review unveiling the critical roles of Fe in enhancing OER activity of Ni and Co based catalysts [J].

Anantharaj, Sengeni ;

Kundu, Subrata ;

Noda, Suguru .

NANO ENERGY, 2021, 80

[4] Strategies and Perspectives to Catch the Missing Pieces in Energy-Efficient Hydrogen Evolution Reaction in Alkaline Media [J].

Anantharaj, Sengeni ;

Noda, Suguru ;

Jothi, Vasanth Rajendiran ;

Yi, SungChul ;

Driess, Matthias ;

Menezes, Prashanth W. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (35) :18981-19006

[5] Amorphous Catalysts and Electrochemical Water Splitting: An Untold Story of Harmony [J].

Anantharaj, Sengeni ;

Noda, Suguru .

SMALL, 2020, 16 (02)

[6] Evolution of layered double hydroxides (LDH) as high performance water oxidation electrocatalysts: A review with insights on structure, activity and mechanism [J].

Anantharaj, Sengeni ;

Karthick, Kannimuthu ;

Kundu, Subrata .

MATERIALS TODAY ENERGY, 2017, 6 :1-26

[7] Principles of Dynamic Heterogeneous Catalysis: Surface Resonance and Turnover Frequency Response [J].

Ardagh, M. Alexander ;

Abdelrahman, Omar A. ;

Dauenhauer, Paul J. .

ACS CATALYSIS, 2019, 9 (08) :6929-6937

[8] Recent advances in ruthenium-based electrocatalysts for the hydrogen evolution reaction [J].

Bae, Seo-Yoon ;

Mahmood, Javeed ;

Jeon, In-Yup ;

Baek, Jong-Beom .

NANOSCALE HORIZONS, 2020, 5 (01) :43-56

[9] Ru-doped 3D flower-like bimetallic phosphide with a climbing effect on overall water splitting [J].

Chen, Ding ;

Lu, Ruihu ;

Pu, Zonghua ;

Zhu, Jiawei ;

Li, Hai-Wen ;

Liu, Fang ;

Hu, Song ;

Luo, Xu ;

Wu, Jinsong ;

Zhao, Yan ;

Mu, Shichun .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2020, 279

[10] Ultralow Ru Loading Transition Metal Phosphides as High-Efficient Bifunctional Electrocatalyst for a Solar-to-Hydrogen Generation System [J].

Chen, Ding ;

Pu, Zonghua ;

Lu, Ruihu ;

Ji, Pengxia ;

Wang, Pengyan ;

Zhu, Jiawei ;

Lin, Can ;

Li, Hai-Wen ;

Zhou, Xiangang ;

Hu, Zhiyi ;

Xia, Fanjie ;

Wu, Jingsong ;

Mu, Shichun .

ADVANCED ENERGY MATERIALS, 2020, 10 (28)

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