Amorphous MoSx nanoparticles grown on cobalt-iron-based needle-like array for high-performance flexible asymmetric supercapacitor

被引:37
作者
Zhao, Yan [1 ]
Wang, Sichao [1 ]
Yuan, Ming [1 ]
Chen, Yuan [1 ]
Huang, Yunpeng [3 ]
Lian, Jiabiao [1 ]
Yang, Shiliu [1 ]
Li, Huaming [1 ]
Wu, Limin [2 ]
机构
[1] Jiangsu Univ, Inst Energy Res, Key Lab Zhenjiang, Zhenjiang 212013, Jiangsu, Peoples R China
[2] Fudan Univ, Dept Mat Sci, Shanghai 200433, Peoples R China
[3] Jiangnan Univ, Sch Chem & Mat Engn, Wuxi 214122, Jiangsu, Peoples R China
基金
中国博士后科学基金; 中国国家自然科学基金;
关键词
Molybdenum disulfide; FeCo-based electrode; Array; Defect; Flexible asymmetric supercapacitor; ELECTRODES; NANOSTRUCTURES; CONSTRUCTION; CAPACITANCE; REDUCTION; FOAM; FE; NI;
D O I
10.1016/j.cej.2020.127927
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Although flexible supercapacitors have important applications, the development of high-performance flexible supercapacitors still remains a critical challenge owing to the low ion diffusion rate, poor electro-conductivity, and limited active defect sites. Herein, we report the first amorphous MoSx nanoparticles grown on crystalline FeCo-based nanoneedles (FC@MS-EG) via an ethylene glycol-induced strategy. The FC@MS-EG electrode presents an unprecedented specific capacitance of 1956 F g(-1) at 1 A g(-1) and over 91.1% of capacitance retention even after 6000 cycles because of the unique morphology, the rich defect sites, the high carrier concentration. The FC@MS-EG//AC asymmetric supercapacitor delivers an ultrahigh specific capacitance of 282 F g(-1) at 1 A g(-1) and an excellent energy density of 88.09 Wh kg(-1) along with a power density of 750 W kg(-1). And the self-assembled flexible all-solid-state supercapacitor device can be easily bent and twisted with negligible electrochemical properties attenuation.
引用
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页数:9
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