Highly regioselective functionalization of aliphatic carbon-hydrogen bonds with a perbromohomoscorpionate copper(I) catalyst

被引：104

作者：

Caballero, A

Díaz-Requejo, MM

Belderraín, TR

Nicasio, MC

Trofimenko, S

Pérez, PJ

机构：

[1] Univ Huelva, Dept Quim & Ciencia Mat, Huelva 21071, Spain

[2] Univ Delaware, Dept Chem & Biochem, Newark, DE 19716 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 06期

关键词：

D O I：

10.1021/ja0291484

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complex TpBr3Cu(NCMe) (1) is an excellent catalyst for the regioselective carbene transfer reaction to tertiary C-H bonds of hydrocarbons, at room temperature, using the readily available ethyl diazoacetate (EDA) as the carbene source. Copyright © 2003 American Chemical Society.

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页码：1446 / 1447

页数：2

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