A novel colorimetric and ratiometric pH sensor with a notably large Stokes shift for sensing extremely alkaline solution

被引：7
作者：
Fang, Guiqian [1 ,2 ,3 ]
Wang, Rang [1 ,2 ,3 ]
Zhan, Dongxue [1 ,2 ,3 ]
Chen, Gaofei [1 ,2 ,3 ]
Huang, Yujun [1 ,2 ,3 ]
Ma, Zihan [1 ,2 ,3 ]
Yao, Qingqiang [1 ,2 ,3 ]
Wu, Zhongyu [1 ,2 ,3 ]
机构：
[1] Shandong First Med Univ & Shandong Acad Med Sci, Inst Mat Med, Jinan 250062, Shandong, Peoples R China
[2] Minist Hlth, Key Lab Biotech Drugs, Jinan 250062, Shandong, Peoples R China
[3] Key Lab Rare Uncommon Dis Shandong Prov, Jinan 250062, Shandong, Peoples R China
来源：
DYES AND PIGMENTS | 2021年 / 190卷
基金：
中国国家自然科学基金;
关键词：
Ratiometric; Colorimetric; Fluorescent sensor; pH; Large Stokes shift; Alkaline solution; PROBE; AIE; UV;
D O I：
10.1016/j.dyepig.2021.109265
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
In this work, a facile hemicyanine-naphthalene-based fluorescent sensor for colorimetric and ratiometric sensing of pH was constructed via a simple synthesis process. Significantly, sensor 3 showed a high sensitivity to extremely alkaline solution and had a notably large Stokes shift (145 nm). Its absorbance and fluorescence enhanced or quenched obviously in the pH range of 5.0?12.0, accompanying with colour change. In addition, the fluorescence intensity increased 727-fold (F440/F710) when the pH was adjusted to 12, indicating that sensor 3 showed great potential in the detection of extremely alkaline solution.
引用
收藏
页数：7
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  • [11] Lipid-conjugated fluorescent pH sensors for monitoring pH changes in reconstituted membrane systems
    Kemmer, Gerdi Christine
    Bogh, Sidsel Ammitzboll
    Urban, Michael
    Palmgren, Michael G.
    Vosch, Tom
    Schiller, Jurgen
    Pomorski, Thomas Gunther
    [J]. ANALYST, 2015, 140 (18) : 6313 - 6320
  • [12] 9-Aryl-1,2-dihydropyrrolo[3,4-b]indolizin-3-one (Seoul-Fluor) as a smart platform for colorful ratiometric fluorescent pH sensors
    Kim, Eunha
    Lee, Sanghee
    Park, Seung Bum
    [J]. CHEMICAL COMMUNICATIONS, 2011, 47 (27) : 7734 - 7736
  • [13] Short-chain lipid-conjugated pH sensors for imaging of transporter activities in reconstituted systems and living cells
    Kuehnel, Ronja Marie
    Grifell-Junyent, Marta
    Jorgensen, Ida Louise
    Kemmer, Gerdi Christine
    Schiller, Juergen
    Palmgren, Michael
    Justesen, Bo Hojen
    Pomorski, Thomas Guenther
    [J]. ANALYST, 2019, 144 (09) : 3030 - 3037
  • [14] Near-infrared pH responsive heptamethine cyanine platforms: Modulating the proton acceptor
    Kurutos, Atanas
    Shindo, Yutaka
    Hiruta, Yuki
    Oka, Kotaro
    Citterio, Daniel
    [J]. DYES AND PIGMENTS, 2020, 181
  • [15] Measuring local pH in electrochemistry
    Monteiro, Mariana C. O.
    Koper, Marc T. M.
    [J]. CURRENT OPINION IN ELECTROCHEMISTRY, 2021, 25
  • [16] A novel colorimetric and fluorescence turn- on pH sensor with a notably large Stokes shift for its application
    Ning, Yaoyao
    Wang, Xiaoqing
    Sheng, Kangjia
    Yang, Lili
    Han, Wei
    Xiao, Chaoni
    Li, Jianli
    Zhang, Yongmin
    Wu, Shaoping
    [J]. NEW JOURNAL OF CHEMISTRY, 2018, 42 (17) : 14510 - 14516
  • [17] An AIE and FRET-based BODIPY sensor with large Stoke shift: Novel pH probe exhibiting application in CO32- detection and living cell imaging
    Qiu, Jiabin
    Jiang, Shengjie
    Guo, Hongyu
    Yang, Fafu
    [J]. DYES AND PIGMENTS, 2018, 157 : 351 - 358
  • [18] A fluorescent bichromophoric "off-on-off' pH probe as a molecular logic device (half-subtractor and digital comparator) operating by controlled PET and ICT processes
    Said, Awad I.
    Georgiev, Nikolai I.
    Bojinov, Vladimir B.
    [J]. DYES AND PIGMENTS, 2019, 162 : 377 - 384
  • [19] Resin bead micro-UV - Visible absorption spectroscopy
    Wong, LS
    Birembaut, F
    Brocklesby, WS
    Frey, JG
    Bradley, M
    [J]. ANALYTICAL CHEMISTRY, 2005, 77 (07) : 2247 - 2251
  • [20] Novel benzimidazole-based ratiometric fluorescent probes for acidic pH
    Wu, Yan-Cheng
    You, Jia-Yi
    Jiang, Kai
    Wu, Han-Qing
    Xiong, Jin-Feng
    Wang, Zhao-Yang
    [J]. DYES AND PIGMENTS, 2018, 149 : 1 - 7
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