The structure of sarcomejine:: An application of long-range 1H-15N correlation at natural abundance

被引：13

作者：

Fokialakis, N

Magiatis, P

Skaltsounis, AL ^{[1
]}

Tillequin, F

Sévenet, T

机构：

[1] Univ Athens, Dept Pharm, Lab Pharmacognosy, GR-15771 Athens, Greece

[2] Univ Paris 05, Fac Pharm, Lab Pharmacognosie, CNRS,UMR 8638, F-75006 Paris, France

[3] CNRS, Inst Chim Subst Nat, F-91190 Gif Sur Yvette, France

来源：

JOURNAL OF NATURAL PRODUCTS | 2000年 / 63卷 / 07期

关键词：

D O I：

10.1021/np000083x

中图分类号：

Q94 [植物学];

学科分类号：

071001 ;

摘要：

A new 4(1H)-quinolinone alkaloid, sarcomejine (1), has been isolated from the bark of Sarcomelicope megistophylla. Its structure has been elucidated on the basis of MS and NMR data and especially with a long-range H-1-N-15 correlation NMR spectrum at natural abundance.

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页码：1004 / 1005

页数：2

相关论文

共 21 条

[1] PLANTS OF NEW-CALEDONIA .92. ALKALOIDS FROM SARCOMELICOPE-LEIOCARPA [J].

BAUDOUIN, G ;

TILLEQUIN, F ;

KOCH, M ;

DAU, METH ;

GUILHEM, J ;

PUSSET, J ;

CHAUVIERE, G .

JOURNAL OF NATURAL PRODUCTS, 1985, 48 (02) :260-265

[2] PLANTS FROM NEW-CALEDONIA .95. ALKALOIDS FROM SARCOMELICOPE-ARGYROPHYLLA [J].

BRUMBOUSQUET, M ;

TILLEQUIN, F ;

KOCH, M ;

SEVENET, T .

PLANTA MEDICA, 1985, 51 (06) :536-537

[3]

BRUMBOUSQUET M, 1988, PLANTA MED, V55, P191

[4] LONG-RANGE H-1-N-15 CORRELATION AT NATURAL-ABUNDANCE USING GRADIENT-ENHANCED INVERSE-DETECTION [J].

CROUCH, RC ;

MARTIN, GE .

JOURNAL OF HETEROCYCLIC CHEMISTRY, 1995, 32 (05) :1665-1669

[5] Megistosarcimine and megistosarconine, two alkaloids from Sarcomelicope megistophylla [J].

Fokialakis, N ;

Mitaku, S ;

Mikros, E ;

Skaltsounis, AL ;

Tillequin, F ;

Sevenet, T .

PHYTOCHEMISTRY, 1999, 52 (08) :1745-1748

[6] Low-level long-range 1H-15N heteronuclear shift correlation at natural abundance using submicro NMR techniques [J].

Hadden, CE ;

Martin, GE .

JOURNAL OF NATURAL PRODUCTS, 1998, 61 (08) :969-972

[7]

HARTLEY T G, 1986, Bulletin du Museum National d'Histoire Naturelle Section B Adansonia Botanique Phytochimie, V8, P183

[8] Agrocybenine, novel class alkaloid from the Korean mushroom Agrocybe cylindracea [J].

Koshino, H ;

Lee, IK ;

Kim, JP ;

Kim, WG ;

Uzawa, J ;

Yoo, ID .

TETRAHEDRON LETTERS, 1996, 37 (26) :4549-4550

[9] N-15 chemical shifts and long-range H-1-N-15 coupling pathways of selected Strychnos alkaloids [J].

Martin, GE ;

Crouch, RC ;

Andrews, CW .

JOURNAL OF HETEROCYCLIC CHEMISTRY, 1995, 32 (06) :1759-1766

[10] Long-range H-1-N-15 couplings and N-15 chemical shift assignments of the bis-indole anticancer drug Navelbine(R) [J].

Martin, GE ;

Crouch, RC .

JOURNAL OF HETEROCYCLIC CHEMISTRY, 1995, 32 (06) :1839-1842