Thermodynamics of halogen bonded monolayer self-assembly at the liquid-solid interface

被引：37
|
作者：
Song, W. [1 ,2 ,3 ]
Martsinovich, N. [4 ]
Heckl, W. M. [1 ,2 ,3 ,5 ]
Lackinger, M. [1 ,2 ,3 ,5 ]
机构：
[1] Tech Univ Munich, Dept Phys, D-85748 Garching, Germany
[2] Nanosyst Initiat Munich, D-80799 Munich, Germany
[3] Ctr NanoSci CeNS, D-80799 Munich, Germany
[4] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England
[5] Deutsch Museum, D-80538 Munich, Germany
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 88期
关键词：
SIGMA-HOLE; ACID; FORCE;
D O I：
10.1039/c4cc06251e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Mono layer self-assembly of a hexabrominated, three-fold symmetric aromatic molecule is studied at the heptanoic acid-graphite interface. Thermodynamical insights are obtained from an adapted Born-Haber cycle that is utilized to derive the overall enthalpy change including solvent effects. Comparison with theoretical entropy estimates suggests a minor influence of solvation.
引用
收藏
页码：13465 / 13468
页数：4
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