Efficient heterogeneous oxidation of alkylarenes with molecular oxygen

被引：91

作者：

Kamata, K

Kasai, J

Yamaguchi, K

Mizuno, N

机构：

[1] Japan Sci & Technol Agcy, Core Res Evolut Sci & Technol, Kawaguchi, Saitama 3320012, Japan

[2] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan

来源：

ORGANIC LETTERS | 2004年 / 6卷 / 20期

关键词：

D O I：

10.1021/ol0485363

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ru(OH)(x)/Al2O3 efficiently catalyzes the heterogeneous aerobic oxygenation or oxidative dehydrogenation of alkylarenes to give the corresponding oxygenated or dehydrogenated products. Catalyst/product separation is very easy, and the recovered catalyst is reusable with retention of the high catalytic performance.

引用

收藏

页码：3577 / 3580

页数：4

相关论文

共 27 条

[1] High-performance, solution-processed organic thin film transistors from a novel pentacene precursor [J].

Afzali, A ;

Dimitrakopoulos, CD ;

Breen, TL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (30) :8812-8813

[2]

Anastas P. T., 1998, GREEN CHEM THEORY PR

[3] The role of catalysis in the design, development, and implementation of green chemistry [J].

Anastas, PT ;

Bartlett, LB ;

Kirchhoff, MM ;

Williamson, TC .

CATALYSIS TODAY, 2000, 55 (1-2) :11-22

[4] Activation of nitrous oxide and selective oxidation of alcohols and alkylarenes catalyzed by the [PV2Mo10O40]5- polyoxometalate ion [J].

Ben-Daniel, R ;

Neumann, R .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (01) :92-95

[5] Low-voltage organic transistors on plastic comprising high-dielectric constant gate insulators [J].

Dimitrakopoulos, CD ;

Purushothaman, S ;

Kymissis, J ;

Callegari, A ;

Shaw, JM .

SCIENCE, 1999, 283 (5403) :822-824

[6] REACTIONS OF WEAK CARBON ACIDS UNDER PHASE-TRANSFER CATALYSIS CONDITIONS - OXIDATIONS AND HYDROGEN-DEUTERIUM EXCHANGE [J].

FELDMAN, D ;

RABINOVITZ, M .

JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (16) :3779-3784

[7] DEHYDROGENATION OF POLYCYCLIC HYDROAROMATIC COMPOUNDS [J].

FU, PP ;

HARVEY, RG .

CHEMICAL REVIEWS, 1978, 78 (04) :317-361

[8] Selective nitrous oxide oxidation for C-H oxidation and aromatization of 9,10-dihydroanthracene derivatives [J].

Hashimoto, K ;

Tanaka, H ;

Ikeno, T ;

Yamada, T .

CHEMISTRY LETTERS, 2002, (06) :582-583

[9] Organic synthesis in subcritical water - Oxidation of alkyl aromatics [J].

Holliday, RL ;

Jong, BYM ;

Kolis, JW .

JOURNAL OF SUPERCRITICAL FLUIDS, 1998, 12 (03) :255-260

[10] A NOVEL CATALYSIS OF N-HYDROXYPHTHALIMIDE IN THE OXIDATION OF ORGANIC SUBSTRATES BY MOLECULAR-OXYGEN [J].

ISHII, Y ;

NAKAYAMA, K ;

TAKENO, M ;

SAKAGUCHI, S ;

IWAHAMA, T ;

NISHIYAMA, Y .

JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (13) :3934-3935