Lone pair-π interaction-induced generation of photochromic coordination networks with photoswitchable conductance

被引：82

作者：

Liao, Jian-Zhen ^{[1
,2
]}

Chang, Jian-Fei ^{[1
,2
,3
]}

Meng, Lingyi ^{[1
,2
,4
]}

Zhang, Hai-Long ^{[1
,2
]}

Wang, Sa-Sa ^{[1
,2
]}

Lu, Can-Zhong ^{[1
,2
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Fujian, Peoples R China

[3] Grad Univ Chinese Acad Sci, Beijing 100049, Peoples R China

[4] Chinese Acad Sci, Haixi Inst, Xiamen Inst Rare Earth Mat, Xiamen 361021, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 70期

基金：

中国国家自然科学基金;

关键词：

METAL-ORGANIC FRAMEWORK; TOTAL-ENERGY CALCULATIONS; WAVE BASIS-SET; CHARGE-TRANSFER; ELECTRON-TRANSFER; ANION-PI; NANOPARTICLE NETWORK; NAPHTHALENE DIIMIDES; PHASE-TRANSITIONS; HYBRID MATERIAL;

D O I：

10.1039/c7cc05150f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Lone pair-pi interaction-induced charge-transfer was successfully used for switching the conductance of a coordination network, through variation of the degree of charge transfer caused by external photostimulation. The underlying mechanism is attributed to the changes in efficient charge-carriers by photoinduced strong charge transfer, which was investigated by in situ UV-Vis absorption, ESR, and computational studies.

引用

页码：9701 / 9704

页数：4

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