Extraction and separation of Ga(III) from hydrochloric acid solution by Cyanex-921 in sulfonated kerosene

被引：6

作者：

Ahmed, Ismail Mohamed ^{[1
]}

Ismail, Zeinab Hassanien ^{[1
]}

Hamed, Mostafa Mohamed ^{[1
]}

机构：

[1] Atom Energy Author, Hot Labs Ctr, Cairo 13759, Egypt

来源：

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY | 2018年 / 317卷 / 02期

关键词：

Solvent extraction; Ga(III); CYANEX; 921; Sulfonated kerosene; HCl medium; SOLVENT-EXTRACTION; COEXTRACTABLE IMPURITIES; PHOSPHORIC-ACID; RECOVERY; GALLIUM; DILUENT; ZINC; CHLOROFORM; URANIUM; MEDIA;

D O I：

10.1007/s10967-018-5977-z

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Solvent extraction of Ga(III) from hydrochloric acid solution using CYANEX 921 in sulfonated kerosene as a modified diluent has been discussed. The factors affecting the extraction of gallium have been investigated. The sulfonation of kerosene was found to enhance the separation of gallium from the interfering ions and was examined using IR spectroscopy. The process was found to be exothermic with decrease in the randomness of the system and the extracted species was suggested to be , where refers to the CYANEX 921. The developed method was applied for the separation of Ga(III) from copper and zinc in chloride solution that result during production of Ga-66/68 from the cyclotron.

引用

页码：969 / 976

页数：8

共 23 条

[11] Liquid-liquid extraction and recovery of gallium(III) from acid media with 2-octylaminopyridine in chloroform: analysis of bauxite ore [J].

Mahamuni, Sandip V. ;

Wadgaonkar, Prakash P. ;

Anuse, Mansing A. .

JOURNAL OF THE SERBIAN CHEMICAL SOCIETY, 2010, 75 (08) :1099-1113

[12]

Marczenko Z., 1976, SPECTROPHOTOMETRIC D

[13] The solvent extraction of zinc, cadmium and chromium from phosphoric acid solutions by tri-n butyl phosphate in kerosene diluent [J].

Mellah, Abdelhamid ;

Benachour, Djafer .

SEPARATION AND PURIFICATION TECHNOLOGY, 2007, 56 (02) :220-224

[14] Selective Extraction of Indium(III) and Gallium(III) with 2-Ethylhexyl Thioglycolate [J].

Miura, Rieko ;

Tokumaru, Megumi ;

Oshima, Tatsuya ;

Baba, Yoshinari .

SOLVENT EXTRACTION RESEARCH AND DEVELOPMENT-JAPAN, 2017, 24 :123-130

[15] Gallium: the backbone of the electronics industry [J].

Moskalyk, RR .

MINERALS ENGINEERING, 2003, 16 (10) :921-929

[16] History of Gallium-Nitride-Based Light-Emitting Diodes for Illumination [J].

Nakamura, Shuji ;

Krames, Michael R. .

PROCEEDINGS OF THE IEEE, 2013, 101 (10) :2211-2220

[17] Recovery of zinc(II) from HCI spent pickling solutions by solvent extraction [J].

Regel, M ;

Sastre, AM ;

Szymanowski, J .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2001, 35 (03) :630-635

[18]

Rydberg J, 1992, PRINCIPLES PRACTICES, P129

[19] Rapid separation of 67,68Ga from 68Zn target using precipitation technique [J].

Sadeghi, M. ;

Mokhtari, L. .

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2010, 284 (02) :471-473

[20] Mutual separation of indium(III), gallium(III) and zinc(II) with alkylated aminophosphonic acids with different basicities of amine moiety [J].

Sasaki, Yuji ;

Oshima, Tatsuya ;

Baba, Yoshinari .

SEPARATION AND PURIFICATION TECHNOLOGY, 2017, 173 :37-43

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