Preparation of Pt/MgO/CNT hybrid catalysts and their electrocatalytic properties for ethanol electrooxidation

被引：45

作者：

Liu, B. ^{[1
]}

Chen, J. H. ^{[1
]}

Xiao, C. H. ^{[1
]}

Cui, K. Z. ^{[1
]}

Yang, L. ^{[1
]}

Pang, H. L. ^{[1
]}

Kuang, Y. F. ^{[1
]}

机构：

[1] Hunan Univ, Coll Chem & Chem Engn, Res Inst Appl Electrochem, Changsha 410082, Peoples R China

来源：

ENERGY & FUELS | 2007年 / 21卷 / 03期

关键词：

D O I：

10.1021/ef060452i

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Pt/MgO/CNT hybrid electrocatalysts for ethanol electrooxidation were simply prepared in this paper. The micrograph and elemental compositions of Pt/MgO/CNT catalysts were characterized by scanning electron microscopy and energy-dispersive X-ray spectroscopy, respectively. The electrocatalytic properties of the Pt/MgO/CNT catalyst for ethanol oxidation have been investigated by cyclic voltammetry in 1.0 mol L-1 CH3CH2OH and 1.0 mol L-1 KOH aqueous solution. The effect of the content of MgO on the electrocatalytic activity of the Pt/MgO/CNT catalyst was also investigated. Under the same Pt loading mass and experimental conditions for ethanol oxidation, the Pt/MgO/CNT catalyst shows higher electrocatalytic activity than the Pt/CNT catalyst. Additionally, the Pt/MgO/CNT catalyst possesses a good antipoisoning ability.

引用

页码：1365 / 1369

页数：5

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