A highly active Au/Al2O3 catalyst for cyclohexane oxidation using molecular oxygen

被引：93

作者：

Xu, Li-Xin ^{[1
]}

He, Chao-Hong ^{[1
]}

Zhu, Ming-Qiao ^{[1
]}

Fang, Sheng ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem & Biochem Engn, Hangzhou 310027, Peoples R China

来源：

CATALYSIS LETTERS | 2007年 / 114卷 / 3-4期

基金：

中国国家自然科学基金;

关键词：

gold catalyst; selective oxidation; cyclohexane; alumina;

D O I：

10.1007/s10562-007-9058-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The selective oxidation of cyclohexane to cyclohexanone and cyclohexanol has been investigated over Au/Al2O3 catalysts using molecular oxygen in a solvent-free system. The catalysts were prepared by a modified direct anionic exchange method and characterized by AAS, N-2 adsorption and TEM. The results showed that the catalytic performance of Au/Al2O3 is very high in terms of turnover frequency. Moreover, the nano-size effect of gold is also reported in the reaction.

引用

页码：202 / 205

页数：4

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