Intramolecular hydrogen bonding effect on metal ion complexation of homooxacalix[4]arene bearing tetraamides

被引:14
|
作者
No, K [1 ]
Lee, JH
Yang, SH
Noh, KH
Lee, SW
Kim, JS
机构
[1] Dankook Univ, Dept Chem, Seoul 140714, South Korea
[2] Sungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea
[3] Konyang Univ, Dept Chem, Nonsan 320711, South Korea
[4] Sookmyung Womens Univ, Dept Chem, Seoul 140742, South Korea
关键词
calix[4]arenes; homooxacalixarenes; metal ion complexation;
D O I
10.1016/S0040-4020(03)00281-3
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
N,N-Dipentylamido homooxacalix[4]arene (3) in the C-1,2-alternate conformation provided Pb2+ ion selectivity over other metal cations. N-Monopentylamido homooxacalix[4]arene in C-1,2-alternate conformation has an intramolecular hydrogen bonding, causing decrease of the metal ion complex ability. (C) 2003 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:2403 / 2407
页数:5
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