One-pot synthesis of sulfones via Ni(II)-catalyzed sulfonylation of boronic acids, Na2S2O5 and benzylic ammonium salts

被引：10

作者：

Zhu, Haibo ^{[1
,2
]}

Liu, Yishuai ^{[2
]}

Zhang, Yingying ^{[2
]}

Yang, Liu ^{[2
]}

Meng, Jia ^{[2
]}

Li, Qian ^{[2
]}

Gong, Bozhen ^{[2
]}

Xie, Zongbo ^{[2
]}

Le, Zhang-Gao ^{[2
]}

机构：

[1] East China Univ Technol, Jiangxi Prov Key Lab Polymer Micro Nano Mfg & Dev, Nanchang 330013, Jiangxi, Peoples R China

[2] East China Univ Technol, Jiangxi Prov Key Lab Synthet Chem, Sch Chem Biol & Mat Sci, Nanchang 330013, Jiangxi, Peoples R China

来源：

MOLECULAR CATALYSIS | 2021年 / 505卷

基金：

中国国家自然科学基金;

关键词：

Sulfones; C-N cleavage; C-S formation; Nickel catalysis; Boronic acids;

D O I：

10.1016/j.mcat.2021.111500

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A one-pot nickel-catalyzed synthesis of (hetero)aryl alkyl sulfones from readily available boronic acids, sodium metabisulfite and benzylic ammonium salts as electrophiles is described. This general and efficient synthetic process is of broad scope, occurs in two steps, and delivers structural diverse sulfones, and the intermediate sulfinate is isolated. The transformation exhibits application of benzylic ammonium salts as novel electrophiles for direct insertion of SO2 as a novel area to be investigated.

引用

页数：5

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