Synthesis, Crystal Structure and Magnetic Properties of a Novel Copper Inverse-9-metallacrown-3 Complex

被引：0

作者：

Liu Guang-Xiang ^{[1
]}

Xu Huan-Min ^{[1
]}

Ren Xiao-Ming ^{[1
]}

机构：

[1] Anqing Normal Univ, Sch Chem & Chem Engn, Anhui Key Lab Funct Coordinat Cpds, Anqing 246003, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2010年 / 29卷 / 07期

基金：

中国国家自然科学基金;

关键词：

cupric complex; crystal structure; magnetism; DI-2-PYRIDYL KETONE OXIME; CARBOXYLATE CHEMISTRY; TRINUCLEAR; CORE; TETRANUCLEAR;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of phenyl 2-pyridyl ketoxime (PhPyCNOH) with Cu(NO3)(2)center dot 3H(2)O has led to a triangular complex Cu-3(OH)(PhPyCNO)(3)(NO3)center dot NO3 center dot H2O 1 containing the [Cu-3(mu(2)-OH)](5+) core and possessing the very rare inverse 9-metallacrown-3 motif created by the bridging oximate groups. Crystallographic data for 1: C36H30N8O11Cu3, M-r = 941.30, monoclinic, space group C2/c, a = 18.815(9), b = 33.888(15), c = 14.307(7) angstrom, beta = 118.945(6)degrees, V = 7983(6) angstrom(3), Z= 8, D-c = 1.566 g/cm(3), mu = 1.652 mm(-1), F(000) = 3816, R = 0.0644 and wR = 0.1393 for 3468 observed reflections (I > 2 sigma(I)). Preliminary variable-temperature magnetic susceptibility studies reveal an antiferromagnetically-coupled system showing antisymmetric exchange.

引用

页码：1072 / 1076

页数：5

共 26 条

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