One-Pot Transformation of Simple Furans into 4-Hydroxy-2-cyclopentenones in Water

被引：58

作者：

Kalaitzakis, Dimitris ^{[1
]}

Triantafyllakis, Myron ^{[1
]}

Alexopoulou, Ioanna ^{[1
]}

Sofiadis, Manolis ^{[1
]}

Vassilikogiannakis, Georgios ^{[1
]}

机构：

[1] Univ Crete, Dept Chem, Iraklion 71003, Crete, Greece

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2014年 / 53卷 / 48期

基金：

欧洲研究理事会;

关键词：

cyclopentenones; furan oxidation; intramolecular aldol; singlet oxygen; sustainable chemistry; FATTY-ACID DERIVATIVES; SINGLET-OXYGEN; MARINE SPONGE; 1,4-DICARBONYL COMPOUNDS; GENERAL-SYNTHESIS; PLAKORTIS-SP; CYCLOPENTENONES; ROUTE; PHOTOOXYGENATION; PREDISPOSITION;

D O I：

10.1002/anie.201407477

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A highly efficient one-pot transformation of readily accessible furans into 4-hydroxy-2-cyclopentenones in H2O, using singlet oxygen as oxidant, has been developed.

引用

页码：13201 / 13205

页数：5

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