One-Pot Transformation of Simple Furans into 4-Hydroxy-2-cyclopentenones in Water

被引：58
作者：
Kalaitzakis, Dimitris [1 ]
Triantafyllakis, Myron [1 ]
Alexopoulou, Ioanna [1 ]
Sofiadis, Manolis [1 ]
Vassilikogiannakis, Georgios [1 ]
机构：
[1] Univ Crete, Dept Chem, Iraklion 71003, Crete, Greece
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2014年 / 53卷 / 48期
基金：
欧洲研究理事会;
关键词：
cyclopentenones; furan oxidation; intramolecular aldol; singlet oxygen; sustainable chemistry; FATTY-ACID DERIVATIVES; SINGLET-OXYGEN; MARINE SPONGE; 1,4-DICARBONYL COMPOUNDS; GENERAL-SYNTHESIS; PLAKORTIS-SP; CYCLOPENTENONES; ROUTE; PHOTOOXYGENATION; PREDISPOSITION;
D O I：
10.1002/anie.201407477
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A highly efficient one-pot transformation of readily accessible furans into 4-hydroxy-2-cyclopentenones in H2O, using singlet oxygen as oxidant, has been developed.
引用
收藏
页码：13201 / 13205
页数：5
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