Crystal chemistry of lead oxide hydroxide nitrates I.: The crystal structure of [Pb6O4](OH)(NO3)(CO3)

被引：39
|
作者：
Li, YP
Krivovichev, SV
Burns, PC
机构：
[1] St Petersburg State Univ, Dept Crystallog, St Petersburg 199034, Russia
[2] Univ Notre Dame, Dept Civil Engn & Geol Sci, Notre Dame, IN 46556 USA
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2000年 / 153卷 / 02期
关键词：
lead nitrate carbonate; oxocentered tetrahedra; polynuclear lead oxo/hydroxo clusters;
D O I：
10.1006/jssc.2000.8784
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The new lead oxide hydroxide nitrate carbonate, [Pb6O4](OH)(NO3)(CO3), has been synthesized by hydrothermal methods. The crystal structure has been determined by single-crystal X-ray diffraction and refined to R1 = 0.030. The compound is orthorhombic, space group Pnma, a = 30.557(6), b = 5.809(1), and c = 7.183(2) Angstrom, V = 1274.9(5) Angstrom(3), Z = 4. The structure consists of (OPb4) oxocentered tetrahedra linked via edges into double [O2Pb3] chains running along the b axis. These chains are linked via (OH)Pb-2 dimers into layers parallel to the (100) plane. (NO3) and (CO3) groups are parallel to the (010) plane and are located between the Pb-(O, OH) layers. Pb coordination polyhedra are strongly distorted due to the influence of lone-pair electrons. The presence of the nitrate, carbonate, and (OH)(-) groups has been confirmed by Fourier transform infrared spectroscopy, (C) 2000 Academic Press.
引用
收藏
页码：365 / 370
页数：6
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