Solid-state 207Pb NMR studies of mixed lead halides, PbFX (X = Cl, Br, or I)

被引:6
|
作者
Glatfelter, Alicia
Dybowski, Cecil [1 ]
Kragten, David D.
Bai, Shi
Perry, Dale L.
Lockard, Jenny
机构
[1] Univ Delaware, Dept Chem & Biochem, Newark, DE 19716 USA
[2] Univ Delaware, Dept Chem Engn, Newark, DE 19716 USA
[3] Lawrence Berkeley Natl Lab, Berkeley, CA 94720 USA
基金
美国国家科学基金会;
关键词
synthesis; materials; lead(II); lead(II) fluoride chloride; lead(II) fluoride bromide; lead(II) fluoride iodide; photo-active; photo-sensitive; light-sensitive; PbFCl; PbFBr; PbFI; sensor;
D O I
10.1016/j.saa.2006.06.002
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
Solid-state Pb-207 NMR studies have been conducted on mixed lead(II) halides of the type PbFX, where X = Cl, Br, or I. NMR data for the mixed halides are compared to the solid-state NMR data for the divalent, binary lead halides, PbX2 (X = F, Cl, Br, I). The NMR data are evaluated in the context of the structures of the compounds and the effects of the mixed halides on the electronic structure of the divalent lead. Data sets for the mixed halides are discussed and compared to those for the regular lead(II) halides. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:1361 / 1363
页数:3
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