Mechanochemical modification of properties and reactivity of nanosized arsenic sulphide As4S4

被引：18
|
作者：
Balaz, P. [1 ]
Choi, W. S.
Dutkova, E.
机构：
[1] Slovak Acad Sci, Inst Geotech, Kosice 04353, Slovakia
[2] Pusan Natl Univ, Dept Pharmaceut Mfg, Pusan 609735, South Korea
[3] Pusan Natl Univ, Interdisciplinary Program Powder Technol, Pusan 609735, South Korea
来源：
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 2007年 / 68卷 / 5-6期
关键词：
chalcogenides; chemical synthesis; Raman spectroscopy; X-ray diffraction; surface properties;
D O I：
10.1016/j.jpcs.2007.01.008
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The effect of high-energy milling of arsenic sulphide As4S4 on its phase transition has been studied. The transition of alpha-As4S4 to the high- temperature beta-As4S4 as well as the formation of As4S4 nanosize powder (16-48 nm) has been described. The presence of beta-As4S4 has been proven by X-ray diffraction (XRD) and Raman spectroscopy. The fine particles were characterized by measurement of specific surface area and particle size distribution. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1178 / 1183
页数：6
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