Mechanochemical modification of properties and reactivity of nanosized arsenic sulphide As4S4

被引：18

作者：

Balaz, P. ^{[1
]}

Choi, W. S.

Dutkova, E.

机构：

[1] Slovak Acad Sci, Inst Geotech, Kosice 04353, Slovakia

[2] Pusan Natl Univ, Dept Pharmaceut Mfg, Pusan 609735, South Korea

[3] Pusan Natl Univ, Interdisciplinary Program Powder Technol, Pusan 609735, South Korea

来源：

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 2007年 / 68卷 / 5-6期

关键词：

chalcogenides; chemical synthesis; Raman spectroscopy; X-ray diffraction; surface properties;

D O I：

10.1016/j.jpcs.2007.01.008

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The effect of high-energy milling of arsenic sulphide As4S4 on its phase transition has been studied. The transition of alpha-As4S4 to the high- temperature beta-As4S4 as well as the formation of As4S4 nanosize powder (16-48 nm) has been described. The presence of beta-As4S4 has been proven by X-ray diffraction (XRD) and Raman spectroscopy. The fine particles were characterized by measurement of specific surface area and particle size distribution. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：1178 / 1183

页数：6

共 27 条

[11] Determination of nanocrystal sizes:: A comparison of TEM, SAXS, and XRD studies of highly monodisperse COPt3 particles [J].