[Cd16In64S134]44-:: 31-Å tetrahedron with a large cavity

被引：97
作者：
Li, HL
Kim, J
O'Keeffe, M
Yaghi, OM [1 ]
机构：
[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48103 USA
[2] Arizona State Univ, Dept Chem, Tempe, AZ 85287 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 16期
关键词：
clusters; indium; microporous materials; sulfides; supertetrahedra;
D O I：
10.1002/anie.200250748
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The hole story? A super-supertetrahedral anionic cluster of 214 atoms and 80 tetrahedral units is prepared. The crystal structure has finite tetrahedral units of [Cd16In64S134]44- ions composed of four T4 supertetrahedra (see picture). Each cluster is nearly a regular tetrahedron with edge lengths of 31.06 and 31.07 Å, and has large octahedral cavity (yellow sphere).
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收藏
页码：1819 / 1821
页数：3
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