Synthesis and Optical Property of a New Zinc Complex Based on the Derivative of 2-(2′-Hydroxyphenyl)-1H-benzimidazole and Phenanthroline

被引：0
作者：
Yin Guo-Jie [1 ]
Zhang Hao-Yu [1 ]
Tian Wen-Jie [1 ]
Zhao Dan [1 ]
Zhang Bin [2 ]
Chen Dong-Mei [1 ]
机构：
[1] Luoyang Inst Sci & Technol, Sch Environm Engn & Chem, Luoyang 471023, Peoples R China
[2] Zhengzhou Univ, Coll Chem, Zhengzhou 450000, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2021年 / 40卷 / 04期
关键词：
synthesis; proton transfer; intramolecular hydrogen bond; INTRAMOLECULAR PROTON-TRANSFER; EMISSION; LUMINESCENCE; 2-(2'-HYDROXYPHENYL)BENZIMIDAZOLE; BENZIMIDAZOLES; CHROMOPHORES; TAUTOMERISM; ROTAMERISM; FILMS;
D O I：
10.14102/j.cnki.0254-5861.2011-2941
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel zinc complex (ZnE) has been designed and synthesized based on the derivative of 2-(2'-hydroxyphenyl)-1-H-benzimidazole (HBI) and the neutral nitrogen-containing ligand (phen). The crystal of the title complex crystallizes in the monoclinic system, space group P2(1)/n with a = 10.2631(2), b = 34.2166(6), c = 11.4103(3) angstrom, beta = 96.771(2)degrees, M-r = 844.24, V = 3978.99(14) angstrom(3), Z = 4, the final R = 0.0400 and wR = 0.1001 for 8107 observed reflections (I > 2 sigma(I)). In the title complex, the free protonated phenoxide moiety (4-OH) is successfully retained to realize pseudo-intramolecular hydrogen bonds with the coordinated 0 atom from the other ligand.
引用
收藏
页码：487 / 494
页数：8
相关论文
共 43 条
  • [1] [Anonymous], 2009, GAUSSIAN 09
  • [2] [Anonymous], 2013, CRYSALISPRO VERS 1 1
  • [3] White Emitters by Tuning the Excited-State Intramolecular Proton-Transfer Fluorescence Emission in 2-(2′-Hydroxybenzofuran)benzoxazole Dyes
    Benelhadj, Karima
    Muzuzu, Wenziz
    Massue, Julien
    Retailleau, Pascal
    Charaf-Eddin, Azzam
    Laurent, Adele D.
    Jacquemin, Denis
    Ulrich, Gilles
    Ziessel, Raymond
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (40) : 12843 - 12857
  • [4] 2-(2′-Hydroxyphenyl)benzimidazole and 9,10-Phenanthroimidazole Chelates and Borate Complexes: Solution- and Solid-State Emitters
    Benelhadj, Karima
    Massue, Julien
    Retailleau, Pascal
    Ulrich, Gilles
    Ziessel, Raymond
    [J]. ORGANIC LETTERS, 2013, 15 (12) : 2918 - 2921
  • [5] Solvent-Modulated Ground-State Rotamerism and Tautomerism and Excited-State Proton-Transfer Processes in o-Hydroxynaphthylbenzimidazoles
    Brenlla, Alfonso
    Rodriguez-Prieto, Flor
    Mosquera, Manuel
    Rios, Miguel A.
    Rios Rodriguez, M. Carmen
    [J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2009, 113 (01) : 56 - 67
  • [6] Role of nitrogen substitution in phenyl ring on excited state intramolecular proton transfer and rotamerism of 2-(2′-hydroxyphenyl)benzimidazole: A theoretical study
    Chipem, Francis A. S.
    Dash, Nihar
    Krishnamoorthy, G.
    [J]. JOURNAL OF CHEMICAL PHYSICS, 2011, 134 (10)
  • [7] An AIE and ESIPT based kinetically resolved fluorescent probe for biothiols
    Cui, Lei
    Baek, Yeonju
    Lee, Songyi
    Kwon, Nahyun
    Yoon, Juyoung
    [J]. JOURNAL OF MATERIALS CHEMISTRY C, 2016, 4 (14) : 2909 - 2914
  • [8] OLEX2: a complete structure solution, refinement and analysis program
    Dolomanov, Oleg V.
    Bourhis, Luc J.
    Gildea, Richard J.
    Howard, Judith A. K.
    Puschmann, Horst
    [J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2009, 42 : 339 - 341
  • [9] Dreizler R., 1990, Density Functional Theory: An Approach to the Quantum Many-Body Problem
  • [10] Colorless, Transparent, Dye-Doped Polymer Films Exhibiting Tunable Luminescence Color: Controlling the Dual-Color Luminescence of 2-(2′-Hydroxyphenyl)imidazo[1,2-a]pyridine Derivatives with the Surrounding Matrix
    Furukawa, Shintaro
    Shono, Hideaki
    Mutai, Toshiki
    Araki, Koji
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (18) : 16065 - 16070
12345