Structures in Langmuir-Blodgett Films of Amphiphilic Tetrathiafulvalenes and Tetrafluorotetracyanoquinodimethane CT Complex

被引：0

作者：

Tatewaki, Yoko ^{[1
]}

Okada, Shuji ^{[1
]}

Takizawa, Junko ^{[2
]}

Hatanaka, Tatsuya ^{[3
]}

Kimura, Mutsumi ^{[2
,3
]}

Shirai, Hirofusa ^{[2
,3
]}

机构：

[1] Yamagata Univ, Dept Polymer Sci & Engn, Grad Sch Sci & Engn, Yonezawa, Yamagata, Japan

[2] Shinshu Univ, Collaborat Innovat Ctr Nanotech FIBER, Ueda, Nagano, Japan

[3] Shinshu Univ, Fac Text Sci & Technol, Dept Funct Polymer Sci, Ueda, Nagano 386, Japan

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2010年 / 519卷

关键词：

Charge transfer; chirality; helical structures; hydrogen bonds; nanostructures; MOLECULAR NANOWIRES; MACROCYCLES;

D O I：

10.1080/15421401003613584

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An asymmetric TTF derivative 1 having two arms substituted by amide and chiral groups was synthesized and its CT complex with 2,3,5,6-tetrafluoro-7,7',8,8'-tetracyano-p-quinodimethane (1-F(4)TCNQ) were also prepared. Thin film formation at the air-water interface and the film deposition on substrates of 1 and 1-F(4)TCNQ were investigated. When we deposited the film of 1-F(4)TCNQ prepared on pure water onto a mica surface by a single upstroke withdrawal, curved nanowire structures were observed on the thin films. On the contrary, 1 without F(4)TCNQ showed three-dimensional dome structures on the thin films, and the morphologies of the Langmuir-Blodgett (LB) films depended on the existence of F(4)TCNQ. An average dimension of nanowire was 6.0 (height) x 500 (width) x 10000 (length) nm(3).

引用

页码：157 / 162

页数：6

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