Reactivation of a Retarded Suspension of Ground Granulated Blast-Furnace Slag

被引:7
作者
Schneider, Nick [1 ]
Stephan, Dietmar [1 ]
机构
[1] Tech Univ Berlin, Bldg Mat & Construct Chem, Gustav Meyer Allee 25, D-13355 Berlin, Germany
关键词
retardation; reactivation; ground granulated blast-furnace slag; d-gluconic acid; NaOH; hydration study; ALKALI-ACTIVATED SLAG; CEMENT HYDRATION; STRENGTH; MECHANISMS; GLUCONATE; BINDERS; MORTAR;
D O I
10.3390/ma9030174
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
An effective retarded suspension of ground granulated blast-furnace slag (GGBFS) needs a strong activator to reactivate the hydration. In this research study, sodium hydroxide (NaOH) as an alkali activator in two different concentrations (30 and 50 wt.%) was used to overcome the retardation and give the hardened GGBFS the reasonable strength. The study was carried out with a mixture of GGBFS, a solution of 1.0 wt.% d-gluconic acid (C6H12O7) as a retarder in the mixing water and a methyl cellulose as a stabilizer. The reactivation was executed after seven different periods (up to 28 days) after the system was retarded. The following investigations were performed: slump test, measurement of ultrasonic (US) velocity, compressive strength and gross density, thermogravimetry (TG) and scanning electron microscopy (SEM). The analyses of the hardened samples were carried out seven, 28 and 90 days after the reactivation. The result of the study is an effective reactivation of a retarded suspension. In this case, the activator with 50 wt.% NaOH shows a very high performance. The setting time of the reactivated binders is much longer compared to the reference, but, in the longer term, the compressive strength and the progress of the hydration exceed the performance of the reference.
引用
收藏
页数:14
相关论文
共 52 条
[1]   Influence of activator type on hydration kinetics, hydrate assemblage and microstructural development of alkali activated blast-furnace slags [J].
Ben Haha, M. ;
Le Saout, G. ;
Winnefeld, F. ;
Lothenbach, B. .
CEMENT AND CONCRETE RESEARCH, 2011, 41 (03) :301-310
[2]  
Benedix R., 2011, BAUCHEMIE EINFUHRUNG
[3]  
Brothers L. E., 2012, U. S. Patent, Patent No. [8,851,173 9, 8851173]
[4]   Structure, Mechanisms of Reaction, and Strength of an Alkali-Activated Blast-Furnace Slag [J].
Burciaga-Diaz, Oswaldo ;
Ivan Escalante-Garcia, Jose .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2013, 96 (12) :3939-3948
[5]   Ultrasound monitoring of the influence of different accelerating admixtures and cement types for shotcrete on setting and hardening behaviour [J].
De Belie, N ;
Grosse, CU ;
Kurz, J ;
Reinhardt, HW .
CEMENT AND CONCRETE RESEARCH, 2005, 35 (11) :2087-2094
[6]  
EHRENBERG Andreas., 2008, Cement International, V6, P90
[7]  
EHRENBERG Andreas., 2008, Cement International, V6, P82
[8]   Hydration products and reactivity of blast-furnace slag activated by various alkalis [J].
Escalante-García, JI ;
Fuentes, AF ;
Gorokhovsky, A ;
Fraire-Luna, PE ;
Mendoza-Suarez, G .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2003, 86 (12) :2148-2153
[9]   Structure of calcium silicate hydrates formed in alkaline-activated slag:: Influence of the type of alkaline activator [J].
Fernández-Jiménez, A ;
Puertas, F ;
Sobrados, I ;
Sanz, J .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2003, 86 (08) :1389-1394
[10]   Effect of activator mix on the hydration and strength behaviour of alkali-activated slag cements [J].
Fernández-Jiménez, A ;
Puertas, F .
ADVANCES IN CEMENT RESEARCH, 2003, 15 (03) :129-136