Coumarin-Based, Electron-Trapping Iridium Complexes as Highly Efficient and Stable Phosphorescent Emitters for Organic Light-Emitting Diodes

被引:55
作者
Ren, Xiaofan [1 ]
Kondakova, Marina E. [1 ]
Giesen, David J. [1 ]
Rajeswaran, Manju [1 ]
Madaras, Marcel [1 ]
Lenhart, William C. [1 ]
机构
[1] Eastman Kodak Co, Res Labs, Rochester, NY 14650 USA
关键词
REDUCTION; DEVICES;
D O I
10.1021/ic9022097
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A new class of coumarin-based iridium tris-cyclometalated complexes has been developed. These complexes are highly emissive, with emission colors ranging from green to orange-red. Besides modification of ligand structures, color tuning was realized by incorporation of ligands with different electrochemical properties in a heteroleptic structure. The organic light-emitting diodes (OLEDs) using these compounds as emissive dopants are highly efficient and stable. Unlike other Ir(III) phosphorescent dopants, these coumarin-based Ir(III) dopants can effectively trap and transport electrons in the emissive layer.
引用
收藏
页码:1301 / 1303
页数:3
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