Comparison of structures of luminescent silkworm silk prepared by feeding and dyeing

被引:5
作者
Ji, J. Y. [1 ]
Kang, C. M. [1 ]
Li, K. [1 ]
He, J. [1 ]
Ma, Y. [1 ,2 ]
机构
[1] Donghua Univ, Coll Mat Sci & Engn, Shanghai 201620, Peoples R China
[2] Donghua Univ, State Key Lab Modificat Chem Fibers & Polymer Mat, Shanghai 201620, Peoples R China
关键词
Rhodamine B; Feeding; Dyeing; Fluorescence; SURFACE-ACTIVE DYES; FLUOROCARBON GROUPS;
D O I
10.1179/1432891714Z.000000000787
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Silkworm silk is among the most widely used natural fibres for textile and biomedical applications owing to its extraordinary mechanical properties and superior biocompatibility. In this paper, we reported a direct procedure in producing intrinsically luminescent silk by feeding silkworms with Rhodamine B (RhB). We demonstrated that the amount of RhB in fibroin was much more than that in sericin for those silk fibres prepared by feeding (FM-silk). RhB was further successfully introduced into fibroin via dyeing (DM-silk). DM-silk has a bit higher RhB concentration at equilibrium. On the other hand, RhB in FM-silk exhibit better stability arising from hydrogen bonds with fibroin as indicated by FTIR.
引用
收藏
页码:817 / 820
页数:4
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