Oxidative Desulfurization of Naphtha with Hydrogen Peroxide in Presence of Acid Catalyst in Naphtha/Acetic Acid Biphasic System

被引：6

作者：

Yazu, Kazumasa ^{[1
]}

Matsumura, Akimitsu ^{[1
]}

Sato, Shinya ^{[1
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Energy Technol Res Inst, Tsukuba, Ibaraki 3058569, Japan

来源：

JOURNAL OF THE JAPAN PETROLEUM INSTITUTE | 2010年 / 53卷 / 04期

关键词：

Oxidative desulfurization; Naphtha; Hydrogen peroxide; Acetic acid; Thiophene; Hydrodesulfurization; DEEP DESULFURIZATION; MILD OXIDATION; LIQUID-PHASE; THIOPHENE; KINETICS; OIL; MECHANISM; FUELS; TS-1; H2O2;

D O I：

10.1627/jpi.53.251

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Oxidative desulfurization of naphtha with H2O2 in the presence of H2SO4 in the naphtha/acetic acid (AeOH) biphasic system was investigated All organosulfur compounds examined were smoothly oxidized in AeOH by peracetic acid effectively formed from AeOH and H2O2 in the presence of H2SO4 The order of the oxidation reactivities was sulfides, disulfides > benzothiophenes > thiophenes The organosulfur compounds in octane were also oxidized with H2O2 in the presence of H2SO4 in the octane/AeOH biphasic system The oxidation proceeded in the AcOH phase and most of the oxidized sulfur compounds resided in this phase, resulting in the successive removal of the sulfur compounds from the octane phase. This oxidative treatment effectively reduced the sulfur content of naphtha. and adsorption with silica gel further reduced the sulfur content to below 0.5 mass ppm In addition, hydrodesulfurization is an effective pretreatment for this oxidative desulfurization of naphtha, resulting in further reduction of the sulfur content to below 0.1 mass ppm

引用

页码：251 / 255

页数：5

共 16 条

[1] Science and technology of novel processes for deep desulfurization of oil refinery streams: A review
Babich, IV
Moulijn, JA
[J]. FUEL, 2003, 82 (06) : 607 - 631
[2] Mesoporous TS-1: Nanocasting synthesis with CMK-3 as template and its performance in catalytic oxidation of aromatic thiophene
Fang, Yunming
Hu, Haoquan
[J]. CATALYSIS COMMUNICATIONS, 2007, 8 (05) : 817 - 820
[3] Mild oxidation with H2O2 over Ti-containing molecular sieves -: A very efficient method for removing aromatic sulfur compounds from fuels
Hulea, V
Fajula, F
Bousquet, J
[J]. JOURNAL OF CATALYSIS, 2001, 198 (02) : 179 - 186
[4] Mild oxidation of thiophene over TS-1/H2O2
Kong, LY
Li, G
Wang, XS
[J]. CATALYSIS TODAY, 2004, 93-5 : 341 - 345
[5] Kinetics and mechanism of liquid-phase oxidation of thiophene over TS-1 using H2O2 under mild conditions
Kong, LY
Li, G
Wang, XS
[J]. CATALYSIS LETTERS, 2004, 92 (3-4) : 163 - 167
[6] Oxidation of thiophenes over silica gel using hydrogen peroxide and formic acid
Lanju, C.
Shaohui, G.
Dishun, Z.
Jialin, W.
Tong, M.
[J]. ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS, 2008, 30 (04) : 370 - 376
[7] The direct synthesis of hydrogen peroxide from H2 and O2 over Au/TS-1 and application in oxidation of thiophene in situ
Ma, Shuqi
Li, Gang
Wang, Xiangsheng
[J]. CHEMISTRY LETTERS, 2006, 35 (04) : 428 - 429
[8] Oxidative desulfurization of light gas oil and vacuum gas oil by oxidation and solvent extraction
Otsuki, S
Nonaka, T
Takashima, N
Qian, WH
Ishihara, A
Imai, T
Kabe, T
[J]. ENERGY & FUELS, 2000, 14 (06) : 1232 - 1239
[9] Adsorptive separation of infinitesimal sulfur oxide in naphtha - Screening of adsorbents
Sato, Shinya
Yazu, Kazumasa
Matsumura, Akimitsu
[J]. JOURNAL OF THE JAPAN PETROLEUM INSTITUTE, 2006, 49 (04) : 210 - 213
[10] KINETICS OF ACID-CATALYZED FORMATION OF PERACETIC ACID FROM ACETIC ACID AND HYDROGEN PEROXIDE
SAWAKI, Y
OGATA, Y
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1965, 38 (12) : 2103 - +

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