Highly Active CuFeAl-containing Catalysts for Selective Hydrogenation of Furfural to Furfuryl Alcohol

被引：18
作者：
Selishcheva, Svetlana A. [1 ,2 ]
Smirnov, Andrey A. [1 ,2 ]
Fedorov, Alexander, V [1 ,2 ]
Bulavchenko, Olga A. [1 ,2 ]
Saraev, Andrey A. [1 ,2 ]
Lebedev, Maksim Yu [1 ,2 ]
Yakovlev, Vadim A. [1 ,2 ]
机构：
[1] Novosibirsk State Univ, Sci & Educ Ctr Energy Efficient Catalysis, Pirogova Str 1, Novosibirsk 630090, Russia
[2] Boreskov Inst Catalysis, Dept Catalyt Proc Fine & Bioorgan Synth, Fed Res Ctr, Pr Akad Lavrentieva 5, Novosibirsk 630090, Russia
来源：
CATALYSTS | 2019年 / 9卷 / 10期
关键词：
furfural; furfuryl alcohol; CuFe-containing catalyst; hydrogenation; PHASE HYDROGENATION; CU/SIO2; CATALYSTS; CONVERSION; KINETICS; FE;
D O I：
10.3390/catal9100816
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
CuFe-containing catalysts with different copper oxide content were prepared by fusion of metal salts. The obtained catalyst showed high activity in the hydrogenation of furfural to furfuryl alcohol (FA) in the batch reactor in the presence of isopropanol as a solvent at a temperature of 100 degrees C and a hydrogen pressure of 6.0 MPa. The yield of FA and furfural conversion are 97% and 98%, respectively. In the solvent-free reaction in the flow-type reactor; the most active catalyst Cu20Fe66Al14 leads to the 96% formation of FA with 100% conversion of furfural at liquid hourly space velocity (LHSV) = 1 h(-1); 160 degrees C and a hydrogen pressure of 5.0 MPa during 30 h. According to the X-ray diffraction (XRD) method, the active component of the spent and fresh Cu20Fe66Al14 catalyst is the same and is represented by metallic copper and Fe3O4-type spinel. Using different methods, the formation of active sites was investigated.
引用
收藏
页数：20
相关论文
共 38 条
  • [1] Montmorillonite K10-Catalyzed Solvent-Free Conversion of Furfural into Cyclopentenones
    Bonacci, Sonia
    Nardi, Monica
    Costanzo, Paola
    De Nino, Antonio
    Di Gioia, Maria Luisa
    Oliverio, Manuela
    Procopio, Antonio
    [J]. CATALYSTS, 2019, 9 (03):
  • [2] The Influence of Cu and Al Additives on Reduction of Iron(III) Oxide: In Situ XRD and XANES Study
    Bulavchenko, Olga A.
    Vinokurov, Zakhar S.
    Saraev, Andrey A.
    Tsapina, Anna M.
    Trigub, Alexander L.
    Gerasimov, Evgeny Yu.
    Gladky, Alexey Yu.
    Fedorov, Alexander V.
    Yakovlev, Vadim A.
    Kaichev, Vasily V.
    [J]. INORGANIC CHEMISTRY, 2019, 58 (08) : 4842 - 4850
  • [3] Structural Materials Science end-station at the Kurchatov Synchrotron Radiation Source: Recent instrumentation upgrades and experimental results
    Chernyshov, A. A.
    Veligzhanin, A. A.
    Zubavichus, Y. V.
    [J]. NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT, 2009, 603 (1-2) : 95 - 98
  • [4] Use of XPS in the determination of chemical environment and oxidation state of iron and sulfur samples: constitution of a data basis in binding energies for Fe and S reference compounds and applications to the evidence of surface species of an oxidized pyrite in a carbonate medium
    Descostes, M
    Mercier, F
    Thromat, N
    Beaucaire, C
    Gautier-Soyer, M
    [J]. APPLIED SURFACE SCIENCE, 2000, 165 (04) : 288 - 302
  • [5] Catalytic furfural hydrogenation to furfuryl alcohol over Cu/SiO2 catalysts: A comparative study of the preparation methods
    Du, Hong
    Ma, Xiuyun
    Yan, Peifang
    Jiang, Miao
    Zhao, Ziang
    Zhang, Z. Conrad
    [J]. FUEL PROCESSING TECHNOLOGY, 2019, 193 : 221 - 231
  • [6] Catalytic Transfer Hydrogenolysis as an Effective Tool for the Reductive Upgrading of Cellulose, Hemicellulose, Lignin, and Their Derived Molecules
    Espro, Claudia
    Gumina, Bianca
    Szumelda, Tomasz
    Paone, Emilia
    Mauriello, Francesco
    [J]. CATALYSTS, 2018, 8 (08)
  • [7] Structure and Chemistry of Cu-Fe-Al Nanocomposite Catalysts for CO Oxidation
    Fedorov, A. V.
    Tsapina, A. M.
    Bulavchenko, O. A.
    Saraev, A. A.
    Odegova, G. V.
    Ermakov, D. Yu.
    Zubavichus, Y. V.
    Yakovlev, V. A.
    Kaichev, V. V.
    [J]. CATALYSIS LETTERS, 2018, 148 (12) : 3715 - 3722
  • [8] A quantum-chemical study of CO adsorption on small Cu particles supported on reduced SiO2
    Ferullo, RM
    Castellani, NJ
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 234 (1-2) : 121 - 127
  • [9] Kinetic models for hydroconversion of furfural over the ecofriendly Cu-MgO catalyst: An experimental and theoretical study
    Ghashghaee, Mohammad
    Shirvani, Samira
    Ghambarian, Mehdi
    [J]. APPLIED CATALYSIS A-GENERAL, 2017, 545 : 134 - 147
  • [10] Copper(II) Triflate As a Reusable Catalyst for the Synthesis of trans-4,5-Diamino-cyclopent-2-enones in Water
    Gomes, Rafael F. A.
    Esteves, Nuno R.
    Coelho, Jaime A. S.
    Afonso, Carlos A. M.
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2018, 83 (14) : 7509 - 7513
1234