Performance of zinc chlorophyll based molecules for dye sensitized solar cell

被引：11

作者：

Erten-Ela, Sule ^{[1
]}

Ocakoglu, Kasim ^{[2
,3
]}

Tarnowska, Anna ^{[4
]}

Vakuliuk, Olena ^{[4
]}

Gryko, Daniel T. ^{[4
]}

机构：

[1] Ege Univ, Solar Energy Inst, TR-35100 Izmir, Turkey

[2] Mersin Univ, Adv Technol Res & Applicat Ctr, TR-33343 Yenisehir, Mersin, Turkey

[3] Mersin Univ, Tarsus Fac Technol, Dept Energy Syst Engn, TR-33480 Mersin, Turkey

[4] Warsaw Univ Technol, Fac Chem, PL-00664 Warsaw, Poland

来源：

DYES AND PIGMENTS | 2015年 / 114卷

关键词：

Zinc chlorophyll; Dye sensitized solar cell; Nanocrystalline TiO2; AM 1.5 solar irradiation; J-V; IPCE; SOLID-STATE; ELECTRON-TRANSFER; NATURAL DYES; TIO2; DERIVATIVES; COMPLEXES; SYSTEMS; CHAINS; MODEL;

D O I：

10.1016/j.dyepig.2014.11.008

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

In this study, we investigated the influence of long carbon chains in ester group of the zinc chlorophyll derivatives, zinc hexyl 3-devinyl-3-hydroxymethyl-pyropheophorbide-a (ZnChl-C6), zinc octadecyl 3-devinyl-3-hydroxymethyl-pyropheophorbide-a (ZnChl-C18), zinc dodecyl 3-devinyl-3-hydroxymethyl-pyropheophorbide-a (ZnChl-C12) and zinc methyl 3-devinyl-3-methylhydroxymethylpyropheophorbidea (ZnChl-OH), on the DSSC performance. Photovoltaic performances were determined in the order of ZnChlC12 > ZnChlC18 > ZnChlC6 > ZnChlOH from J-V curves. The higher J(sc) obtained from the ZnChl-C12 sensitizer could result from the presence of long alkyl chain which reduce the charge recombination rate and facilitate electron injection. However, it was observed to decrease in the DSSC performance with the presence of longer alkyl chains (>C12). It was understood from the obtained results, the length of the alkyl chains is directly affect the DSSC performance. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：129 / 137

页数：9

共 34 条

[1] Preparation and properties of dye-sensitized solar cell using chlorophyll derivative immobilized TiO2 film electrode [J].

Amao, Y ;

Yamada, Y ;

Aoki, K .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2004, 164 (1-3) :47-51

[2] Donor-p-Acceptors Containing the 10-(1,3-Dithiol-2-ylidene)anthracene Unit for Dye-Sensitized Solar Cells [J].

Bouit, Pierre-Antoine ;

Marszalek, Magdalena ;

Humphry-Baker, Robin ;

Viruela, Rafael ;

Orti, Enrique ;

Zakeeruddin, Shaik M. ;

Graetzel, Michael ;

Delgado, Juan Luis ;

Martin, Nazario .

CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (37) :11621-11629

[3]

Erten-Ela S, MAT SCI SEMICONDUCTO, V27, P532

[4]

Erten-Ela S, SPECTROCHIM ACTA A, V135, P676

[5] Synthesis of novel ruthenium II phenanthroline complex and its application to TiO2 and ZnO nanoparticles on the electrode of dye sensitized solar cells [J].

Erten-Ela, Sule ;

Sogut, Selcan ;

Ocakoglu, Kasim .

MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING, 2014, 23 :159-166

[6] Fabrication of thin film nanocrystalline TiO2 solar cells using ruthenium complexes with carboxyl and sulfonyl groups [J].

Erten-Ela, Sule ;

Ocakoglu, Kasim .

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2014, 20 (02) :474-479

[7] Photoelectrochemical cells [J].

Grätzel, M .

NATURE, 2001, 414 (6861) :338-344

[8] Thiocyanate linkage isomerism in the isobutyl ester form of the ruthenium dye known as N3 [J].

Hue, Ryan ;

Mann, Kent R. ;

Gladfelter, Wayne L. .

JOURNAL OF COORDINATION CHEMISTRY, 2014, 67 (01) :17-28

[9] Chlorin-sensitized high-efficiency photovoltaic cells that mimic spectral response of photosynthesis [J].

Ikegami, Masashi ;

Ozeki, Mayu ;

Kijitori, Yujiro ;

Miyasaka, Tsutomu .

ELECTROCHEMISTRY, 2008, 76 (02) :140-143

[10]

JOHNSON DG, 1988, ISR J CHEM, V28, P193

← 1 2 3 4 →