Self-assembly in organolanthanide chemistry: Formation of rings and clusters

被引：0
|
作者：
Anwander, R [1 ]
机构：
[1] Tech Univ Munich, Inst Anorgan Chem, D-85747 Garching, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1998年 / 37卷 / 05期
关键词：
clusters; cyclopentadienyl complexes; lanthanides; multinuclear complexes; ring structures;
D O I：
10.1002/(SICI)1521-3773(19980316)37:5<599::AID-ANIE599>3.0.CO;2-1
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Highly symmetrical arrangements of the lanthanide metals Ln including the S6-symmetrical chair conformations of the [Sm(CN)]6 ring in 1 or an icosahedron as in 2 are found in novel multinuclear cyclopentadienyl complexes. The formation of different structural motifs is directed by ionic bonding criteria such as the nature of the bridging heteroligands and the Cp/Ln ratio.
引用
收藏
页码：599 / 602
页数：4
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